Highly Selective Chemical Sensing in a Luminescent Nanoporous Magnet (pages 5625–5629)
Jesús Ferrando-Soria, Hossein Khajavi, Pablo Serra-Crespo, Jorge Gascon, Freek Kapteijn, Miguel Julve, Francesc Lloret, Jorge Pasán, Catalina Ruiz-Pérez, Yves Journaux and Emilio Pardo
Version of Record online: 13 AUG 2012 | DOI: 10.1002/adma.201201846
On the road to chemical sensors: A novel 2D oxamato-based manganese(II)-copper(II) mixed-metal–organic framework (M'MOF) exhibiting non-linear fluorescence and long-range magnetic ordering is reported. This new luminescent nanoporous magnet features highly selective solvent- and gas sorption-induced optical switching behavior, opening the door to potential application for sensing of small molecules.