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Highly Efficient Heterogeneous Aqueous Kharasch Reaction with an Amphiphilic Resin-Supported Ruthenium Catalyst

  1. Yohei Oe,
  2. Yasuhiro Uozumi

Article first published online: 10 JUL 2008

DOI: 10.1002/adsc.200800359

Issue

Advanced Synthesis & Catalysis

Advanced Synthesis & Catalysis

Volume 350, Issue 11-12, pages 1771–1775, August 4, 2008

Additional Information

How to Cite

Oe, Y. and Uozumi, Y. (2008), Highly Efficient Heterogeneous Aqueous Kharasch Reaction with an Amphiphilic Resin-Supported Ruthenium Catalyst. Adv. Synth. Catal., 350: 1771–1775. doi: 10.1002/adsc.200800359

Author Information

  1. Institute for Molecular Science (IMS) and CREST, Higashi-yama, Myodaiji, Okazaki 444-8787, Japan, Fax: (+81)-564-59-5574

Publication History

  1. Issue published online: 31 JUL 2008
  2. Article first published online: 10 JUL 2008
  3. Manuscript Revised: 10 JUN 2008
  4. Manuscript Received: 5 MAY 2008

Funded by

  • CREST program
  • MEXT

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Keywords:

  • allylic substitution;
  • aqueous media;
  • asymmetric catalysis;
  • combinatorial chemistry;
  • palladium;
  • polymer-supported catalyst

Abstract

An amphiphilic polystyrene-polyethylene glycol (PS-PEG) resin-supported ruthenium complex was designed and prepared. The polymeric Ru complex was found to promote the transition metal-catalyzed atom transfer radical addition of halogenated compounds to olefins, the Kharasch reaction, in water under heterogeneous as well as AIBN-free conditions with a high level of atom economy to meet green chemical requirements.

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