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Palladium(II)-Phosphine Complexes Supported on Magnetic Nanoparticles: Filtration-Free, Recyclable Catalysts for Suzuki–Miyaura Cross-Coupling Reactions

  1. Sankaranarayanapillai Shylesh,
  2. Lei Wang,
  3. Werner R. Thiel

Article first published online: 10 FEB 2010

DOI: 10.1002/adsc.200900698

Issue

Advanced Synthesis & Catalysis

Advanced Synthesis & Catalysis

Volume 352, Issue 2-3, pages 425–432, February 15, 2010

Additional Information

How to Cite

Shylesh, S., Wang, L. and Thiel, Werner R. (2010), Palladium(II)-Phosphine Complexes Supported on Magnetic Nanoparticles: Filtration-Free, Recyclable Catalysts for Suzuki–Miyaura Cross-Coupling Reactions. Adv. Synth. Catal., 352: 425–432. doi: 10.1002/adsc.200900698

Author Information

  1. Fachbereich Chemie, TU Kaiserslautern, Erwin-Schrödinger-Str., Geb. 54, 67663 Kaiserslautern, Germany, Fax: (+49)-631-205-4676

Publication History

  1. Issue published online: 17 FEB 2010
  2. Article first published online: 10 FEB 2010
  3. Manuscript Revised: 21 DEC 2009
  4. Manuscript Received: 6 OCT 2009

Funded by

  • Alexander von Humboldt-Foundation
  • “NanoKat” at the TU Kaiserslautern

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Keywords:

  • coupling reactions;
  • heterogenization;
  • magnetic nanoparticles;
  • palladium;
  • phosphine ligands

Abstract

An organic-inorganic hybrid heterogeneous nanocatalyst system was synthesized by covalent grafting a palladium dichloride complex of the type (L)2PdCl2 (L=trimethoxysilyl-functionalized triphenylphosphine) on silica-coated magnetic nanoparticles. It is a highly active and recyclable catalyst for the Suzuki–Miyaura cross-coupling reaction. The new catalyst can easily be separated from the reaction mixture by applying an external magnetic field and can be recycled many times without any loss of activity.

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