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Recyclable Heterogeneous Palladium Catalysts in Pure Water: Sustainable Developments in Suzuki, Heck, Sonogashira and Tsuji–Trost Reactions

Authors

  • Marc Lamblin,

    1. Université de Bordeaux; CNRS – UMR 5248, Institut Européen de Chimie et Biologie, 2 rue Robert Escarpit, 33607 Pessac, France
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  • Luma Nassar-Hardy,

    1. Université de Bordeaux; CNRS – UMR 5255, Institut des Sciences Moléculaires, 351 Cours de la Libération, Talence, 33405 France, Fax: : (+33)-540-006-286
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  • Jean-Cyrille Hierso,

    1. Université de Bourgogne, Institut de Chimie Moléculaire de l'Université de Bourgogne, UMR – CNRS 5260, 9 avenue Alain Savary 21078 Dijon, France
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  • Eric Fouquet,

    1. Université de Bordeaux; CNRS – UMR 5255, Institut des Sciences Moléculaires, 351 Cours de la Libération, Talence, 33405 France, Fax: : (+33)-540-006-286
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  • François-Xavier Felpin

    1. Université de Bordeaux; CNRS – UMR 5255, Institut des Sciences Moléculaires, 351 Cours de la Libération, Talence, 33405 France, Fax: : (+33)-540-006-286
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Abstract

This review summarizes the progress made essentially these last ten years on heterogeneous palladium catalysis in pure water. The work covers four important palladium-catalyzed transformations for carbon-carbon bond formation: Suzuki, Heck, Sonogashira and Tsuji–Trost reactions. The discussion focuses on the efficiency and reusability of the heterogeneous catalysts as well as on the experimental conditions from a sustainable chemistry point of view. The review is introduced by a discussion on mechanistic aspects inherent to heterogeneous catalysis.

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