Advanced Synthesis & Catalysis

Copyright © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Cover image for Advanced Synthesis & Catalysis

January 2009

Volume 351, Issue 1-2

Pages 1–286

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Corrigendum
    5. Commentary
    6. Review
    7. Communications
    8. Full Papers
    9. Updates
    1. Cover Picture: (Adv. Synth. Catal. 1-2/2009) (page 1)

      Article first published online: 20 JAN 2009 | DOI: 10.1002/adsc.200990001

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      The cover picture, provided by Maurice S. Brookhart, shows an example of a cationic palladium diimine complex which catalyzes polymerization of ethylene to high molecular weight, highly branched polyethylene. The catalyst resting states are the alkyl ethylene complexes as modeled by the ethyl ethylene complex shown. Migratory insertion of these alkyl ethylene species leads to β-agostic complexes in which palladium can rapidly migrate along the chain (“chain-walking”) through β-elimination/readdition reactions. Trapping of branched alkyl complexes followed by insertion leads to formation of branches in the polymer chain. Polyethylenes formed exhibit branches-on-branches since chain-walking through tertiary centers is facile.

  2. Contents

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Corrigendum
    5. Commentary
    6. Review
    7. Communications
    8. Full Papers
    9. Updates
    1. Graphical Abstract: Adv. Synth. Catal. 1-2/2009 (pages 3–10)

      Article first published online: 20 JAN 2009 | DOI: 10.1002/adsc.200990002

  3. Corrigendum

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Corrigendum
    5. Commentary
    6. Review
    7. Communications
    8. Full Papers
    9. Updates
    1. You have free access to this content
      Retraction: Polymer-Supported N-Phenylsulfonyloxaziridine (Davis Reagent): A Versatile Oxidant (page 10)

      Yongnian Gao and Yulin Lam

      Article first published online: 20 JAN 2009 | DOI: 10.1002/adsc.200990000

      This article corrects:

      Polymer-Supported N-Phenylsulfonyloxaziridine (Davis Reagent): A Versatile Oxidant

      Vol. 350, Issue 18, 2937–2946, Article first published online: 9 DEC 2008

  4. Commentary

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Corrigendum
    5. Commentary
    6. Review
    7. Communications
    8. Full Papers
    9. Updates
    1. Advanced Synthesis & Catalysis – Growing in Size and Impact (pages 25–31)

      Joe P. Richmond

      Article first published online: 20 JAN 2009 | DOI: 10.1002/adsc.200900007

  5. Review

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Corrigendum
    5. Commentary
    6. Review
    7. Communications
    8. Full Papers
    9. Updates
    1. Water in Stereoselective Organocatalytic Reactions (pages 33–57)

      Michelangelo Gruttadauria, Francesco Giacalone and Renato Noto

      Article first published online: 12 JAN 2009 | DOI: 10.1002/adsc.200800731

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  6. Communications

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Corrigendum
    5. Commentary
    6. Review
    7. Communications
    8. Full Papers
    9. Updates
    1. Elucidation of Architectural Requirements from a Spacer in Supported Proline-Based Catalysts of Enantioselective Aldol Reaction (pages 59–65)

      Kerem Goren, Tzofit Kehat and Moshe Portnoy

      Article first published online: 12 JAN 2009 | DOI: 10.1002/adsc.200800734

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    2. Stable and Catalytically Highly Active ansa Compounds with Cycloalkyl Moieties as Bridging Units (pages 66–70)

      Alejandro Capapé, Alexander Raith and Fritz E. Kühn

      Article first published online: 29 DEC 2008 | DOI: 10.1002/adsc.200800559

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    3. The First Thiadiazolidine 1-Oxide System for Phosphine-Free Palladium-Mediated Catalysis (pages 71–77)

      Benjamin R. Buckley and Stephen P. Neary

      Article first published online: 12 JAN 2009 | DOI: 10.1002/adsc.200800522

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    4. A Catalytic Asymmetric Electrocyclization-Protonation Reaction (pages 78–84)

      Magnus Rueping and Winai Ieawsuwan

      Article first published online: 12 JAN 2009 | DOI: 10.1002/adsc.200800623

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    5. A Dramatic Substituent Effect in Silver(I)-Catalyzed Regioselective Cyclization of ortho-Alkynylaryl Aldehyde Oxime Derivatives (pages 85–88)

      Hongyin Gao and Junliang Zhang

      Article first published online: 19 DEC 2008 | DOI: 10.1002/adsc.200800568

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    6. TEMPO-tert-Butyl Nitrite: An Efficient Catalytic System for Aerobic Oxidation of Alcohols (pages 89–92)

      Xijun He, Zhenlu Shen, Weimin Mo, Nan Sun, Baoxiang Hu and Xinquan Hu

      Article first published online: 19 DEC 2008 | DOI: 10.1002/adsc.200800501

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    7. Selective Oxidation of Aromatic Amines to Nitro Derivatives using Potassium Iodide-tert-Butyl Hydroperoxide Catalytic System (pages 93–96)

      K. Rajender Reddy, C. Uma Maheswari, M. Venkateshwar and M. Lakshmi Kantam

      Article first published online: 12 JAN 2009 | DOI: 10.1002/adsc.200800641

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    8. Kinetic Resolutions by Enantioselective Pauson–Khand-Type Reaction (pages 97–102)

      Dong Eun Kim, Jaesung Kwak, In Su Kim and Nakcheol Jeong

      Article first published online: 12 JAN 2009 | DOI: 10.1002/adsc.200800657

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    9. Enantioselective Organocatalytic Michael Addition of α-Substituted Cyanoacetates to α,β-Unsaturated Selenones (pages 103–106)

      Francesca Marini, Silvia Sternativo, Francesca Del Verme, Lorenzo Testaferri and Marcello Tiecco

      Article first published online: 19 DEC 2008 | DOI: 10.1002/adsc.200800592

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    10. Highly Enantio- and Diastereoselective Inverse Electron Demand Hetero-Diels–Alder Reaction using 2-Alkenoylpyridine N-Oxides as Oxo-Heterodienes (pages 107–111)

      Santiago Barroso, Gonzalo Blay, M. Carmen Muñoz and José R. Pedro

      Article first published online: 19 DEC 2008 | DOI: 10.1002/adsc.200800606

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    11. Copper(II)-Catalyzed C[BOND]C Bond-Forming Reactions of α-Electron-Withdrawing Group-Substituted Ketene S,S-Acetals with Carbonyl Compounds and a Facile Synthesis of Coumarins (pages 112–116)

      Hong-Juan Yuan, Mang Wang, Ying-Jie Liu and Qun Liu

      Article first published online: 19 DEC 2008 | DOI: 10.1002/adsc.200800584

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    12. Stereoselective Synthesis of Conjugated Bisallenols as Precursors of Novel Bis(2,5-dihydrofuran) Derivatives (pages 117–122)

      Manojkumar Poonoth and Norbert Krause

      Article first published online: 19 DEC 2008 | DOI: 10.1002/adsc.200800469

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    13. Iron(III) Salt-Catalyzed Nazarov Cyclization/Michael Addition of Pyrrole Derivatives (pages 123–128)

      Masamune Fujiwara, Motoi Kawatsura, Shuichi Hayase, Masato Nanjo and Toshiyuki Itoh

      Article first published online: 19 DEC 2008 | DOI: 10.1002/adsc.200800702

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    14. An Efficient Domino Approach for the Synthesis of Multisubstituted Pyrroles via Gold/Silver-Catalyzed Amination/Cycloisomerization of (Z)-2-En-4-yn-1-ols (pages 129–134)

      Yuhua Lu, Xiaoping Fu, Haoyi Chen, Xiangwei Du, Xueshun Jia and Yuanhong Liu

      Article first published online: 19 DEC 2008 | DOI: 10.1002/adsc.200800490

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    15. Lewis Acid-Mediated Selective Cycloadditions of Vinylidenecyclopropanes with Aromatic Aldehydes: An Efficient Protocol for the Synthesis of Benzo[c]fluorene, Furan and Furo[2,3-b]furan Derivatives (pages 135–140)

      Chenliang Su and Xian Huang

      Article first published online: 12 JAN 2009 | DOI: 10.1002/adsc.200800661

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    16. One-Pot Synthesis of Highly Substituted Allenylidene Derivatives via Palladium- or Nickel-Catalyzed Tandem Michael Addition–Cyclization Reaction (pages 141–146)

      Yun Shi, Jing Huang, Yan-Fang Yang, Lu-Yong Wu, Yan-Ning Niu, Peng-Fei Huo, Xue-Yuan Liu and Yong-Min Liang

      Article first published online: 2 JAN 2009 | DOI: 10.1002/adsc.200800582

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    17. Titanium(IV)/Tridentate BINOL Derivative as Catalyst for meso-Aziridine Ring-Opening Reactions: High Enantioselectivity, Strong Positive Non-Linear Effect and Structural Characterization (pages 147–152)

      Rongmin Yu, Yasuhiro Yamashita and Shū Kobayashi

      Article first published online: 19 DEC 2008 | DOI: 10.1002/adsc.200800402

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    18. Ruthenium-Catalyzed C[BOND]H Bond Activation of Michael Acceptors: An Unusual Reactivity Leading to Allylsilanes (pages 153–157)

      Marc-Olivier Simon, Rémi Martinez, Jean-Pierre Genêt and Sylvain Darses

      Article first published online: 12 JAN 2009 | DOI: 10.1002/adsc.200800600

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    19. Highly Efficient Organocatalyzed Direct Asymmetric Aldol Reactions of Hydroxyacetone and Aldehydes (pages 158–162)

      Xiaoyu Wu, Zhixiong Ma, Zhengqing Ye, Shan Qian and Gang Zhao

      Article first published online: 2 JAN 2009 | DOI: 10.1002/adsc.200800558

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  7. Full Papers

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Corrigendum
    5. Commentary
    6. Review
    7. Communications
    8. Full Papers
    9. Updates
    1. Photooxidation of Benzyl Alcohols with Immobilized Flavins (pages 163–174)

      Harald Schmaderer, Petra Hilgers, Robert Lechner and Burkhard König

      Article first published online: 12 JAN 2009 | DOI: 10.1002/adsc.200800576

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    2. Reduction of Alkyl Halides by Triethylsilane Based on a Cationic Iridium Bis(phosphinite) Pincer Catalyst: Scope, Selectivity and Mechanism (pages 175–187)

      Jian Yang and Maurice Brookhart

      Article first published online: 19 DEC 2008 | DOI: 10.1002/adsc.200800528

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    3. Highly Active and Recyclable Heterogeneous Iridium Pincer Catalysts for Transfer Dehydrogenation of Alkanes (pages 188–206)

      Zheng Huang, Maurice Brookhart, Alan S. Goldman, Sabuj Kundu, Amlan Ray, Susannah L. Scott and Brian C. Vicente

      Article first published online: 2 JAN 2009 | DOI: 10.1002/adsc.200800615

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    4. Copper Nanoparticles on Charcoal for Multicomponent Catalytic Synthesis of 1,2,3-Triazole Derivatives from Benzyl Halides or Alkyl Halides, Terminal Alkynes and Sodium Azide in Water as a “Green” Solvent (pages 207–218)

      Hashem Sharghi, Reza Khalifeh and Mohammad Mahdi Doroodmand

      Article first published online: 12 JAN 2009 | DOI: 10.1002/adsc.200800612

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    5. Hybrid Inorganic-Organic Materials Carrying Tertiary Amine and Thiourea Residues Tethered on Mesoporous Silica Nanoparticles: Synthesis, Characterization, and Co-Operative Catalysis (pages 219–229)

      Alessandra Puglisi, Rita Annunziata, Maurizio Benaglia, Franco Cozzi, Antonella Gervasini, Vittorio Bertacche and Maria Chiara Sala

      Article first published online: 12 JAN 2009 | DOI: 10.1002/adsc.200800635

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    6. Retraction: An Efficient Synthesis of Poly(ethylene glycol)-Supported Iron(II) Porphyrin using a Click Reaction and its Application for the Catalytic Olefination of Aldehydes (pages 230–234)

      Suman L. Jain, Jomy K. Joseph, Fritz E. Kühn and Oliver Reiser

      Article first published online: 12 JAN 2009 | DOI: 10.1002/adsc.200800361

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      Corrected by:

      Retraction: Retraction: An Efficient Synthesis of Poly(ethylene glycol)-Supported Iron(II) Porphyrin using a Click Reaction and its Application for the Catalytic Olefination of Aldehydes

      Vol. 353, Issue 8, 1391, Article first published online: 24 MAY 2011

    7. Kinetic Study of the Asymmetric Hydrogenation of Methyl Acetoacetate in the Presence of a Ruthenium Binaphthophosphepine Complex (pages 235–245)

      Eva Öchsner, Bastian Etzold, Kathrin Junge, Matthias Beller and Peter Wasserscheid

      Article first published online: 19 DEC 2008 | DOI: 10.1002/adsc.200800531

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    8. Highly Efficient Iron(II) Chloride/N-Bromosuccinimide-Mediated Synthesis of Imides and Acylsulfonamides (pages 246–252)

      Feng Wang, Hongxia Liu, Hua Fu, Yuyang Jiang and Yufen Zhao

      Article first published online: 12 JAN 2009 | DOI: 10.1002/adsc.200800668

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    9. Stereoselective Synthesis of Three Isomers of tert-Butyl 5-Hydroxy-4-methyl-3-oxohexanoate through Alcohol Dehydrogenase-Catalyzed Dynamic Kinetic Resolution (pages 253–259)

      Steffen Lüdeke, Michael Richter and Michael Müller

      Article first published online: 2 JAN 2009 | DOI: 10.1002/adsc.200800619

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    10. An N-Linked Bidentate Phosphoramidite Ligand (N-Me-BIPAM) for Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to N-Sulfonylarylaldimines (pages 260–270)

      Kazunori Kurihara, Yasunori Yamamoto and Norio Miyaura

      Article first published online: 29 DEC 2008 | DOI: 10.1002/adsc.200800631

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  8. Updates

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Corrigendum
    5. Commentary
    6. Review
    7. Communications
    8. Full Papers
    9. Updates
    1. A Straightforward Procedure for the [2+2+2] Cycloaddition of Enediynes (pages 271–275)

      Anaïs Geny, Sophie Gaudrel, Franck Slowinski, Muriel Amatore, Gaëlle Chouraqui, Max Malacria, Corinne Aubert and Vincent Gandon

      Article first published online: 29 DEC 2008 | DOI: 10.1002/adsc.200800646

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    2. The Ion Tag Strategy as a Route to Highly Efficient Organocatalysts for the Direct Asymmetric Aldol Reaction (pages 276–282)

      Marco Lombardo, Srinivasan Easwar, Filippo Pasi and Claudio Trombini

      Article first published online: 2 JAN 2009 | DOI: 10.1002/adsc.200800608

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    3. An Improved Process for the N-Demethylation of Opiate Alkaloids using an Iron(II) Catalyst in Acetate Buffer (pages 283–286)

      Gaik Kok, Trent D. Ashton and Peter J. Scammells

      Article first published online: 2 JAN 2009 | DOI: 10.1002/adsc.200800632

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