Advanced Synthesis & Catalysis

Cover image for Vol. 351 Issue 11‐12

August 2009

Volume 351, Issue 11-12

Pages 1701–2038

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Communications
    5. Retraction
    6. Communications
    7. Full Papers
    8. Update
    1. Cover Picture: (Adv. Synth. Catal. 11-12/2009) (page 1701)

      Article first published online: 14 AUG 2009 | DOI: 10.1002/adsc.200990021

      Thumbnail image of graphical abstract

      The cover picture, provided by Maurice S. Brookhart, shows an example of a cationic palladium diimine complex which catalyzes polymerization of ethylene to high molecular weight, highly branched polyethylene. The catalyst resting states are the alkyl ethylene complexes as modeled by the ethyl ethylene complex shown. Migratory insertion of these alkyl ethylene species leads to β-agostic complexes in which palladium can rapidly migrate along the chain (“chain-walking”) through β-elimination/readdition reactions. Trapping of branched alkyl complexes followed by insertion leads to formation of branches in the polymer chain. Polyethylenes formed exhibit branches-on-branches since chain-walking through tertiary centers is facile.

  2. Contents

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Communications
    5. Retraction
    6. Communications
    7. Full Papers
    8. Update
    1. Graphical Abstract: Adv. Synth. Catal. 11-12/2009 (pages 1703–1712)

      Article first published online: 14 AUG 2009 | DOI: 10.1002/adsc.200990022

  3. Communications

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Communications
    5. Retraction
    6. Communications
    7. Full Papers
    8. Update
    1. Aminations of Aryl Bromides in Water at Room Temperature (pages 1717–1721)

      Bruce H. Lipshutz, David W. Chung and Brian Rich

      Article first published online: 16 JUL 2009 | DOI: 10.1002/adsc.200900323

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  4. Retraction

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Communications
    5. Retraction
    6. Communications
    7. Full Papers
    8. Update
    1. Retraction: Iron-Catalyzed Suzuki–Miyaura Cross-Coupling Reaction (pages 1732–1736)

      David Bézier and Christophe Darcel

      Article first published online: 27 JUL 2009 | DOI: 10.1002/adsc.200900281

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      Corrected by:

      Retraction: Retraction: Iron-Catalyzed Suzuki–Miyaura Cross-Coupling Reaction

      Vol. 352, Issue 6, 1081, Article first published online: 15 APR 2010

  5. Communications

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Communications
    5. Retraction
    6. Communications
    7. Full Papers
    8. Update
    1. Imidazolium-2-Carboxylate as an Efficient, Expeditious and Eco-Friendly Organocatalyst for Glycerol Carbonate Synthesis (pages 1753–1756)

      Prashant U. Naik, Laetitia Petitjean, Karima Refes, Michel Picquet and Laurent Plasseraud

      Article first published online: 27 JUL 2009 | DOI: 10.1002/adsc.200900280

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    2. Nanoparticle Supported, Magnetically Recoverable Oxodiperoxo Molybdenum Complexes: Efficient Catalysts for Selective Epoxidation Reactions (pages 1789–1795)

      Sankaranarayanapillai Shylesh, Julia Schweizer, Serhiy Demeshko, Volker Schünemann, Stefan Ernst and Werner R. Thiel

      Article first published online: 5 AUG 2009 | DOI: 10.1002/adsc.200900416

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    3. Kinetic Resolution of P-Chirogenic Compounds by Palladium-Catalyzed Alcoholysis of Vinyl Ethers (pages 1796–1800)

      Hisashi Itoh, Eiji Yamamoto, Shigeyuki Masaoka, Ken Sakai and Makoto Tokunaga

      Article first published online: 16 JUL 2009 | DOI: 10.1002/adsc.200900304

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    4. Unprecedent Chemo- and Stereoselective Palladium-Catalysed Methoxycarbonylation of Norbornene (pages 1813–1816)

      Carolina Blanco, Aurora Ruiz, Cyril Godard, Nicolas Fleury-Brégeot, Angela Marinetti and Carmen Claver

      Article first published online: 7 JUL 2009 | DOI: 10.1002/adsc.200900025

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  6. Full Papers

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Communications
    5. Retraction
    6. Communications
    7. Full Papers
    8. Update
    1. Stability of Second Generation Grubbs’ Alkylidenes to Primary Amines: Formation of Novel Ruthenium-Amine Complexes (pages 1817–1825)

      Gerald O. Wilson, Keith A. Porter, Haim Weissman, Scott R. White, Nancy R. Sottos and Jeffrey S. Moore

      Article first published online: 31 JUL 2009 | DOI: 10.1002/adsc.200900134

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    2. On the Mechanism of Biotransformation of the Anthraquinonic Dye Acid Blue 62 by Laccases (pages 1857–1865)

      Luciana Pereira, Ana V. Coelho, Cristina A. Viegas, Christelle Ganachaud, Gilles Iacazio, Thierry Tron, M. Paula Robalo and Lígia O. Martins

      Article first published online: 21 JUL 2009 | DOI: 10.1002/adsc.200900271

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    3. Prevention of Manganese Precipitation during the Continuous Selective Partial Oxidation of Methyl Aromatics with Molecular Oxygen in Supercritical Water (pages 1866–1876)

      Joan Fraga-Dubreuil, Eduardo Garcia-Verdugo, Paul A. Hamley, Eduardo Perez, Ian Pearson, W. Barry Thomas, Duncan Housley, Walt Partenheimer and Martyn Poliakoff

      Article first published online: 27 JUL 2009 | DOI: 10.1002/adsc.200900143

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    4. Highly Selective Oxidation of Alkylphenols to Benzoquinones with Hydrogen Peroxide over Silica-Supported Titanium Catalysts: Titanium Cluster Site versus Titanium Single Site (pages 1877–1889)

      Oxana A. Kholdeeva, Irina D. Ivanchikova, Matteo Guidotti, Claudio Pirovano, Nicoletta Ravasio, Marina V. Barmatova and Yurii A. Chesalov

      Article first published online: 27 JUL 2009 | DOI: 10.1002/adsc.200900109

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    5. Efficient Aerobic Oxidation of Alcohols using a Hydrotalcite-Supported Gold Nanoparticle Catalyst (pages 1890–1896)

      Takato Mitsudome, Akifumi Noujima, Tomoo Mizugaki, Koichiro Jitsukawa and Kiyotomi Kaneda

      Article first published online: 31 JUL 2009 | DOI: 10.1002/adsc.200900239

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    6. Ketonization of 1,5-Cyclooctadiene by Nitrous Oxide (pages 1905–1911)

      Dmitry P. Ivanov, Konstantin A. Dubkov, Dmitry E. Babushkin, Sergey V. Semikolenov and Gennady I. Panov

      Article first published online: 13 AUG 2009 | DOI: 10.1002/adsc.200900278

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    7. Hydrogenation of Phenol in Supercritical Carbon Dioxide Catalyzed by Palladium Supported on Al-MCM-41: A Facile Route for One-Pot Cyclohexanone Formation (pages 1912–1924)

      M. Chatterjee, H. Kawanami, M. Sato, A. Chatterjee, T. Yokoyama and T. Suzuki

      Article first published online: 7 JUL 2009 | DOI: 10.1002/adsc.200900144

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    8. Zinc-Salen-Catalyzed Asymmetric Alkynylation of Alkyl Acylsilanes (pages 1955–1960)

      Feng-Quan Li, Shi Zhong, Gui Lu and Albert S. C. Chan

      Article first published online: 16 JUL 2009 | DOI: 10.1002/adsc.200900177

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    9. Synthesis of Chiral 2-Phospha[3]ferrocenophanes and their Behaviour as Organocatalysts in [3+2] Cyclization Reactions (pages 1968–1976)

      Arnaud Voituriez, Armen Panossian, Nicolas Fleury-Brégeot, Pascal Retailleau and Angela Marinetti

      Article first published online: 31 JUL 2009 | DOI: 10.1002/adsc.200900193

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    10. A Highly Efficient Synthesis of a Naphthalenoid Histamine-3 Antagonist (pages 2024–2030)

      Yi-Yin Ku, Tim Grieme, Yu-Ming Pu and Ashok V. Bhatia

      Article first published online: 7 JUL 2009 | DOI: 10.1002/adsc.200900162

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  7. Update

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Communications
    5. Retraction
    6. Communications
    7. Full Papers
    8. Update

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