Advanced Synthesis & Catalysis

Cover image for Vol. 351 Issue 16

November 2009

Volume 351, Issue 16

Pages 2533–2728

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Corrigenda
    5. Communications
    6. Full Papers
    7. Updates
    1. Cover Picture: (Adv. Synth. Catal. 16/2009) (page 2533)

      Version of Record online: 5 NOV 2009 | DOI: 10.1002/adsc.200990028

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      The cover picture, provided by Maurice S. Brookhart, shows an example of a cationic palladium diimine complex which catalyzes polymerization of ethylene to high molecular weight, highly branched polyethylene. The catalyst resting states are the alkyl ethylene complexes as modeled by the ethyl ethylene complex shown. Migratory insertion of these alkyl ethylene species leads to β-agostic complexes in which palladium can rapidly migrate along the chain (“chain-walking”) through β-elimination/readdition reactions. Trapping of branched alkyl complexes followed by insertion leads to formation of branches in the polymer chain. Polyethylenes formed exhibit branches-on-branches since chain-walking through tertiary centers is facile.

  2. Contents

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Corrigenda
    5. Communications
    6. Full Papers
    7. Updates
  3. Corrigenda

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Corrigenda
    5. Communications
    6. Full Papers
    7. Updates
    1. You have free access to this content
      Zinc-Salen-Catalyzed Asymmetric Alkynylation of Alkyl Acylsilanes (page 2541)

      Feng-Quan Li, Shi Zhong, Gui Lu and Albert S. C. Chan

      Version of Record online: 5 NOV 2009 | DOI: 10.1002/adsc.200990030

      This article corrects:

      Zinc-Salen-Catalyzed Asymmetric Alkynylation of Alkyl Acylsilanes

      Vol. 351, Issue 11-12, 1955–1960, Version of Record online: 16 JUL 2009

    2. You have free access to this content
  4. Communications

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Corrigenda
    5. Communications
    6. Full Papers
    7. Updates
    1. Asymmetric Hydrogenation of Quinoxalines Catalyzed by Iridium/PipPhos (pages 2549–2552)

      Nataša Mršić, Thomas Jerphagnon, Adriaan J. Minnaard, Ben L. Feringa and Johannes G. de Vries

      Version of Record online: 28 OCT 2009 | DOI: 10.1002/adsc.200900522

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    2. Highly Efficient Synthesis of Quaternary α-Hydroxy Phosphonates via Lewis Acid-Catalyzed Hydrophosphonylation of Ketones (pages 2567–2572)

      Xin Zhou, Yanling Liu, Lu Chang, Jiannan Zhao, Deju Shang, Xiaohua Liu, Lili Lin and Xiaoming Feng

      Version of Record online: 28 OCT 2009 | DOI: 10.1002/adsc.200900531

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    3. An Organocatalytic Synthesis of cis-N-Alkyl- and N-Arylaziridine Carboxylates (pages 2579–2588)

      Sean P. Bew, Rachel Carrington, David L. Hughes, John Liddle and Paolo Pesce

      Version of Record online: 21 OCT 2009 | DOI: 10.1002/adsc.200900474

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    4. Room Temperature Lewis Base-Catalyzed Alumination of Terminal Alkynes (pages 2595–2598)

      Yuhan Zhou, Thomas Lecourt and Laurent Micouin

      Version of Record online: 21 OCT 2009 | DOI: 10.1002/adsc.200900414

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    5. Silver-Catalyzed Intramolecular Cyclization of o-(1-Alkynyl)benzamides: Efficient Synthesis of (1H)-Isochromen-1-imines (pages 2605–2610)

      Guannan Liu, Yu Zhou, Deju Ye, Dengyou Zhang, Xiao Ding, Hualiang Jiang and Hong Liu

      Version of Record online: 21 OCT 2009 | DOI: 10.1002/adsc.200900381

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    6. Preparation of 2H-1,4-Benzoxazin-2-one Derivatives under Heterogeneous Conditions via Domino Process (pages 2611–2614)

      Roberto Ballini, Alessandro Palmieri, Mohammad AbdulKarim Talaq and Serena Gabrielli

      Version of Record online: 28 OCT 2009 | DOI: 10.1002/adsc.200900627

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    7. Palladium-Catalyzed Annulation of 2-(1-Alkynyl)benzenamines with Disulfides: Synthesis of 3-Sulfenylindoles (pages 2615–2618)

      Yan-Jin Guo, Ri-Yuan Tang, Jin-Heng Li, Ping Zhong and Xing-Guo Zhang

      Version of Record online: 21 OCT 2009 | DOI: 10.1002/adsc.200900055

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    8. Direct Preparation of 7-Allyl- and 7-Arylindolines (pages 2619–2623)

      Daniele Leonori and Iain Coldham

      Version of Record online: 28 OCT 2009 | DOI: 10.1002/adsc.200900499

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  5. Full Papers

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Corrigenda
    5. Communications
    6. Full Papers
    7. Updates
    1. Aerobic Oxidation of Benzylic Alcohols in Water by 2,2,6,6-Tetramethylpiperidine-1-oxyl (TEMPO)/Copper(II) 2-N-Arylpyrrolecarbaldimino Complexes (pages 2625–2632)

      Paweł J. Figiel, Ahlam Sibaouih, Jahir Uddin Ahmad, Martin Nieger, Minna T. Räisänen, Markku Leskelä and Timo Repo

      Version of Record online: 28 OCT 2009 | DOI: 10.1002/adsc.200900478

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    2. Reusable Copper-Aluminum Hydrotalcite/rac-BINOL System for Room Temperature Selective Aerobic Oxidation of Alcohols (pages 2633–2637)

      M. Lakshmi Kantam, R. Arundhathi, Pravin R. Likhar and D. Damodara

      Version of Record online: 28 OCT 2009 | DOI: 10.1002/adsc.200900405

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    3. Metal-Free: An Efficient and Selective Catalytic Aerobic Oxidation of Hydrocarbons with Oxime and N-Hydroxyphthalimide (pages 2638–2642)

      Gengxiu Zheng, Chunhong Liu, Qiufen Wang, Mingyu Wang and Guanyu Yang

      Version of Record online: 28 OCT 2009 | DOI: 10.1002/adsc.200900509

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    4. Direct Amide Synthesis from Alcohols and Amines by Phosphine-Free Ruthenium Catalyst Systems (pages 2643–2649)

      Subhash Chandra Ghosh, Senthilkumar Muthaiah, Yao Zhang, Xiangya Xu and Soon Hyeok Hong

      Version of Record online: 21 OCT 2009 | DOI: 10.1002/adsc.200900482

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    5. Magnetic Nanoparticle Supported Second Generation Hoveyda–Grubbs Catalyst for Metathesis of Unsaturated Fatty Acid Esters (pages 2650–2656)

      Zhu Yinghuai, Loo Kuijin, Ng Huimin, Li Chuanzhao, Ludger Paul Stubbs, Chia Fu Siong, Tan Muihua and Ship Chee Peng

      Version of Record online: 28 OCT 2009 | DOI: 10.1002/adsc.200900370

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    6. Synthesis of Biaryls and Aryl Ketones via Microwave-Assisted Decarboxylative Cross-Couplings (pages 2667–2674)

      Lukas J. Gooßen, Bettina Zimmermann, Christophe Linder, Nuria Rodríguez, Paul P. Lange and Jens Hartung

      Version of Record online: 22 OCT 2009 | DOI: 10.1002/adsc.200900337

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    7. New Indenylidene-Schiff Base-Ruthenium Complexes for Cross-Metathesis and Ring-Closing Metathesis (pages 2689–2701)

      Ana M. Lozano Vila, Stijn Monsaert, Renata Drozdzak, Stanislaw Wolowiec and Francis Verpoort

      Version of Record online: 21 OCT 2009 | DOI: 10.1002/adsc.200900477

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    8. Multicatalytic Tandem Reactions of 2-Alkynylbenzaldoximes with Isocyanides (pages 2702–2708)

      Zhiyuan Chen, Xingxin Yu, Mingchao Su, Xiaodi Yang and Jie Wu

      Version of Record online: 28 OCT 2009 | DOI: 10.1002/adsc.200900442

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    9. Copper-Catalyzed Efficient Multicomponent Reaction: Synthesis of Benzoxazoline-Amidine Derivatives (pages 2709–2713)

      Yongjia Shang, Xinwei He, Jinsong Hu, Jianwei Wu, Min Zhang, Shuyan Yu and Qianqian Zhang

      Version of Record online: 28 OCT 2009 | DOI: 10.1002/adsc.200900525

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  6. Updates

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Corrigenda
    5. Communications
    6. Full Papers
    7. Updates

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