Advanced Synthesis & Catalysis

Copyright © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Cover image for Vol. 351 Issue 7‐8

May 2009

Volume 351, Issue 7-8

Pages 949–1166

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Corrigendum
    5. Commentary
    6. Reviews
    7. Communications
    8. Full Papers
    9. Updates
    1. Cover Picture: (Adv. Synth. Catal. 7-8/2009) (page 949)

      Article first published online: 12 MAY 2009 | DOI: 10.1002/adsc.200990012

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      The cover picture, provided by Maurice S. Brookhart, shows an example of a cationic palladium diimine complex which catalyzes polymerization of ethylene to high molecular weight, highly branched polyethylene. The catalyst resting states are the alkyl ethylene complexes as modeled by the ethyl ethylene complex shown. Migratory insertion of these alkyl ethylene species leads to β-agostic complexes in which palladium can rapidly migrate along the chain (“chain-walking”) through β-elimination/readdition reactions. Trapping of branched alkyl complexes followed by insertion leads to formation of branches in the polymer chain. Polyethylenes formed exhibit branches-on-branches since chain-walking through tertiary centers is facile.

  2. Contents

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Corrigendum
    5. Commentary
    6. Reviews
    7. Communications
    8. Full Papers
    9. Updates
    1. Graphical Abstract: Adv. Synth. Catal. 7-8/2009 (pages 951–956)

      Article first published online: 12 MAY 2009 | DOI: 10.1002/adsc.200990013

  3. Corrigendum

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Corrigendum
    5. Commentary
    6. Reviews
    7. Communications
    8. Full Papers
    9. Updates
    1. You have free access to this content
      Alternation of Chemoselective Control in Stille–Heck and Heck–Stille Reaction Sequences (page 956)

      Kye-Simeon Masters and Bernard L. Flynn

      Article first published online: 12 MAY 2009 | DOI: 10.1002/adsc.200990014

      The communication by Kye-Simeon Masters and Bernard L. Flynn in Issue 4, 2009, pp. 530–536 (DOI: 10.1002/adsc.200800678), should have appeared in this issue dedicated to Professor Armin de Meijere. It was published in Issue 4, 2009, by mistake. On the title page, below the received and publication dates, the following dedication should appear: “Dedicated to Professor Armin de Meijere on the occasion of his 70th birthday.” The editorial office apologizes for this mistake.

      This article corrects:

      Alternation of Chemoselective Control in Stille–Heck and Heck–Stille Reaction Sequences

      Vol. 351, Issue 4, 530–536, Article first published online: 13 FEB 2009

  4. Commentary

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Corrigendum
    5. Commentary
    6. Reviews
    7. Communications
    8. Full Papers
    9. Updates
    1. You have free access to this content
      Professor Armin de Meijere, Practical Elegance in Organic Chemistry (pages 961–962)

      Ryoji Noyori

      Article first published online: 12 MAY 2009 | DOI: 10.1002/adsc.200900172

       

  5. Reviews

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Corrigendum
    5. Commentary
    6. Reviews
    7. Communications
    8. Full Papers
    9. Updates
    1. The Enantioselective Addition of Alkyne Nucleophiles to Carbonyl Groups (pages 963–983)

      Barry M. Trost and Andrew H. Weiss

      Article first published online: 26 FEB 2009 | DOI: 10.1002/adsc.200800776

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    2. Copper-Mediated Aryl-Aryl Couplings for the Construction of Oligophenylenes and Related Heteroaromatics (pages 984–998)

      Masahiko Iyoda

      Article first published online: 29 APR 2009 | DOI: 10.1002/adsc.200900048

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  6. Communications

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Corrigendum
    5. Commentary
    6. Reviews
    7. Communications
    8. Full Papers
    9. Updates
    1. Palladium-Catalyzed Cyclopropanation of Unsaturated Endoperoxides. A New Peroxide-Preserving Reaction (pages 999–1004)

      Michael A. Emerzian, William Davenport, Jiangao Song, Jim Li and Ihsan Erden

      Article first published online: 29 APR 2009 | DOI: 10.1002/adsc.200800804

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    2. Stereoselective Synthesis of Metalated Cyclobutyl Derivatives (pages 1005–1008)

      Einav Tsoglin, Helena Chechik, Guy Karseboom, Nicka Chinkov, Amnon Stanger and Ilan Marek

      Article first published online: 29 APR 2009 | DOI: 10.1002/adsc.200800719

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    3. Expanding the Suzuki–Heck-Type Coupling Cascade: A New Indeno[1,2,3]-Annelation of Polycyclic Aromatic Hydrocarbons (pages 1009–1013)

      Jennifer M. Quimby and Lawrence T. Scott

      Article first published online: 17 MAR 2009 | DOI: 10.1002/adsc.200900018

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    4. Enantioselective Copper-Catalyzed Allylic Substitution Reaction with Aminohydroxyphosphine Ligand (pages 1014–1018)

      Naohiko Yoshikai, Kotaro Miura and Eiichi Nakamura

      Article first published online: 5 MAY 2009 | DOI: 10.1002/adsc.200900054

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    5. Use of the Chiral Pool – Practical Asymmetric Organocatalytic Strecker Reaction with Quinine (pages 1019–1024)

      Rüdiger Reingruber, Thomas Baumann, Stefan Dahmen and Stefan Bräse

      Article first published online: 5 MAY 2009 | DOI: 10.1002/adsc.200800798

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    6. Selective Oxidative Ligand Coupling of Organoborates Bearing an Alkynyl Group (pages 1025–1028)

      Toru Amaya, Yusuke Tsukamura and Toshikazu Hirao

      Article first published online: 5 MAY 2009 | DOI: 10.1002/adsc.200800781

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    7. A Lutidine-Bridged Bis-Perimidinium Salt: Synthesis and Application as a Precursor in Palladium-Catalyzed Cross-Coupling Reactions (pages 1029–1034)

      Tao Tu, Jagadeesh Malineni, Xiaoling Bao and Karl Heinz Dötz

      Article first published online: 5 MAY 2009 | DOI: 10.1002/adsc.200800768

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    8. Comparison of the Relative Reactivities of the Triisopropylsilyl Group With Two Fluorous Analogs (pages 1035–1040)

      Amador Garcia Sancho, Xiao Wang, Bin Sui and Dennis P. Curran

      Article first published online: 5 MAY 2009 | DOI: 10.1002/adsc.200900061

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  7. Full Papers

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Corrigendum
    5. Commentary
    6. Reviews
    7. Communications
    8. Full Papers
    9. Updates
    1. Selective Preparation of Diamondoid Fluorides[1] (pages 1041–1054)

      Hartmut Schwertfeger, Christian Würtele, Heike Hausmann, Jeremy E. P. Dahl, Robert M. K. Carlson, Andrey A. Fokin and Peter R. Schreiner

      Article first published online: 7 APR 2009 | DOI: 10.1002/adsc.200800787

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    2. Convenient Enantioselective Hydrosilylation of Ketones Catalyzed by Zinc-Macrocyclic Oligoamine Complexes (pages 1055–1063)

      Jadwiga Gajewy, Marcin Kwit and Jacek Gawroński

      Article first published online: 7 APR 2009 | DOI: 10.1002/adsc.200800801

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    3. Copper-Catalyzed N-Arylation/Hydroamin(d)ation Domino Synthesis of Indoles and its Application to the Preparation of a Chek1/KDR Kinase Inhibitor Pharmacophore (pages 1064–1072)

      Lutz Ackermann, Sebastian Barfüßer and Harish K. Potukuchi

      Article first published online: 30 APR 2009 | DOI: 10.1002/adsc.200900004

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    4. Synthesis of 2,6-Dioxo-1,2,3,4,5,6-hexahydroindoles by Acid- Catalyzed Cyclization of Acetal-Protected (2,4-Dioxocyclohex-1-yl)acetamides and their Transformation into 5,8,9,10-Tetrahydro-6H-indolo[2,1-a]isoquinolin-9-ones (pages 1073–1079)

      Benard Juma, Muhammad Adeel, Alexander Villinger, Helmut Reinke, Anke Spannenberg, Christine Fischer and Peter Langer

      Article first published online: 2 FEB 2009 | DOI: 10.1002/adsc.200800691

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    5. Reaction of Bis(alkynyl)silanes with Tris(pentafluorophenyl)borane: Synthesis of Bulky Silole Derivatives by Means of 1,1-Carboboration under Mild Reaction Conditions (pages 1080–1088)

      Gereon Dierker, Juri Ugolotti, Gerald Kehr, Roland Fröhlich and Gerhard Erker

      Article first published online: 30 APR 2009 | DOI: 10.1002/adsc.200900029

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    6. Stereochemical Control by an Ester Group or Olefin Ligand in Platinum-Catalyzed Carboalkoxylation of 6-(1-Alkoxyethoxy)- hex-2-ynoates (pages 1089–1100)

      Itaru Nakamura, Ching Siew Chan, Toshiharu Araki, Masahiro Terada and Yoshinori Yamamoto

      Article first published online: 5 MAY 2009 | DOI: 10.1002/adsc.200800772

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    7. Synthesis of Fluorenes via the Palladium-Catalyzed 5-exo-dig Annulation of o-Alkynylbiaryls (pages 1101–1114)

      Natalia Chernyak and Vladimir Gevorgyan

      Article first published online: 5 MAY 2009 | DOI: 10.1002/adsc.200800765

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    8. First Transformation of Unsaturated Fatty Esters Involving Enyne Cross-Metathesis (pages 1115–1122)

      Virginie Le Ravalec, Cédric Fischmeister and Christian Bruneau

      Article first published online: 7 APR 2009 | DOI: 10.1002/adsc.200800726

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    9. Water versus Solvent-Free Conditions for the Enantioselective Inter- and Intramolecular Aldol Reaction Employing L-Prolinamides and L-Prolinethioamides as Organocatalysts (pages 1123–1131)

      Diana Almaşi, Diego A. Alonso, Andrea-Nekane Balaguer and Carmen Nájera

      Article first published online: 12 MAY 2009 | DOI: 10.1002/adsc.200800814

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    10. Phosphinidene Addition to Conjugated Allenes (pages 1132–1138)

      Federica Bertini, Jan B. M. Wit, Murat Ünal, Franciscus J. J. de Kanter, Marius Schakel, J. Chris Slootweg, Andreas W. Ehlers, Tom Nijbacker, Corine M. D. Komen, Martin Lutz, Anthony L. Spek and Koop Lammertsma

      Article first published online: 30 APR 2009 | DOI: 10.1002/adsc.200900005

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    11. [1.1]Ferrocenophane-1,12-dione as a Precursor of 1,12-Di(cyclopenta-2,4-dienylidene)-[1.1]ferrocenophane, a Doubly Bridged Difulvene (pages 1139–1147)

      José Ramon Garabatos-Perera, Rudolf Wartchow and Holger Butenschön

      Article first published online: 5 MAY 2009 | DOI: 10.1002/adsc.200800780

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    12. Cyclic Enones as Substrates in the Morita–Baylis–Hillman Reaction: Surfactant Interactions, Scope and Scalability with an Emphasis on Formaldehyde (pages 1148–1154)

      Brett D. Schwartz, Achim Porzelle, Kevin S. Jack, Jonathan M. Faber, Ian R. Gentle and Craig M. Williams

      Article first published online: 5 MAY 2009 | DOI: 10.1002/adsc.200800739

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  8. Updates

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Corrigendum
    5. Commentary
    6. Reviews
    7. Communications
    8. Full Papers
    9. Updates
    1. Synthesis of the New 7S-Aminolentiginosine and Derivatives (pages 1155–1161)

      Franca M. Cordero, Paola Bonanno, Sven Neudeck, Carolina Vurchio and Alberto Brandi

      Article first published online: 30 APR 2009 | DOI: 10.1002/adsc.200800806

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    2. Highly Functionalised Enantiopure 4-Hydroxypyridine Derivatives by a Versatile Three-Component Synthesis (pages 1162–1166)

      Christian Eidamshaus and Hans-Ulrich Reissig

      Article first published online: 5 MAY 2009 | DOI: 10.1002/adsc.200800789

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