Advanced Synthesis & Catalysis

Cover image for Vol. 354 Issue 9

June 18, 2012

Volume 354, Issue 9

Pages 1605–1833

  1. Cover Picture

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Review
    5. Communications
    6. Full Papers
    7. Updates
    8. Book Review
    1. You have free access to this content
      Cover Picture: (Adv. Synth. Catal. 9/2012) (page 1605)

      Version of Record online: 14 JUN 2012 | DOI: 10.1002/adsc.201290018

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      On the cover, provided by Vora, Wheeler and Rovis, is depicted a chiral Nheterocyclic carbene catalyst behind a scheme of catalytic intermediates made accessible by this class of compound. Each intermediate – the homoenolate at left, enol azolium at center, and acyl azolium at right – is capable of reacting with an external reagent. The homoenolate can attack an electrophile beta to the starting carbonyl (X), the enol azolium can trap an electrophile alpha (Y), and the acyl azolium can intercept a nucleophile (Z) to release the NHC back into the catalytic cycle. Examples of each reactivity mode depicted on the cover can be found in the accompanying review article.

  2. Contents

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Review
    5. Communications
    6. Full Papers
    7. Updates
    8. Book Review
  3. Review

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Review
    5. Communications
    6. Full Papers
    7. Updates
    8. Book Review
  4. Communications

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Review
    5. Communications
    6. Full Papers
    7. Updates
    8. Book Review
    1. A Scalable, Efficient Gold-Catalyzed Oxidative Phosphonation of sp3 C[BOND]H Bonds using Air as Sustainable Oxidant (pages 1646–1650)

      Jin Xie, Huamin Li, Qicai Xue, Yixiang Cheng and Chengjian Zhu

      Version of Record online: 5 JUN 2012 | DOI: 10.1002/adsc.201200360

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    2. Phosphite-Gold(I)-Catalyzed [2+2] Intermolecular Cycloaddition of Enol Ethers with N-Allenylsulfonamides (pages 1651–1657)

      Samuel Suárez-Pantiga, Cristina Hernández-Díaz, María Piedrafita, Eduardo Rubio and José M. González

      Version of Record online: 5 JUN 2012 | DOI: 10.1002/adsc.201200043

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    3. Gold(I)-Catalyzed Intermolecular [2+2] Cycloadditions between Allenamides and Alkenes (pages 1658–1664)

      Hélio Faustino, Paloma Bernal, Luis Castedo, Fernando López and José L. Mascareñas

      Version of Record online: 5 JUN 2012 | DOI: 10.1002/adsc.201200047

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    4. Enantioselective Synthesis of 4-Isoxazolines by 1,3-Dipolar Cycloadditions of Nitrones to Alkynals Catalyzed by Fluorodiphenylmethylpyrrolidines (pages 1665–1671)

      José Alemán, Alberto Fraile, Leyre Marzo, José Luis García Ruano, Cristina Izquierdo and Sergio Díaz-Tendero

      Version of Record online: 5 JUN 2012 | DOI: 10.1002/adsc.201200033

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    5. Samarium-Promoted Asymmetric Aldol–Tishchenko Reaction: Synthesis of Amino Acid-Derived 4-Amino-1,3-diols (pages 1679–1684)

      Humberto Rodríguez-Solla, Carmen Concellón, Paula Tuya, Santiago García-Granda and M. Rosario Díaz

      Version of Record online: 5 JUN 2012 | DOI: 10.1002/adsc.201100952

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    6. Alkylboronic Esters from Palladium- and Nickel-Catalyzed Borylation of Primary and Secondary Alkyl Bromides (pages 1685–1691)

      Jun Yi, Jin-Hui Liu, Jun Liang, Jian-Jun Dai, Chu-Ting Yang, Yao Fu and Lei Liu

      Version of Record online: 30 MAY 2012 | DOI: 10.1002/adsc.201200136

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    7. Palladium-Catalyzed Selective C[BOND]H Benzylation towards Functionalized Azoles with a Quaternary Carbon Center (pages 1692–1700)

      Pan Xie, Hanmin Huang, Yinjun Xie, Shengmei Guo and Chungu Xia

      Version of Record online: 5 JUN 2012 | DOI: 10.1002/adsc.201200025

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    8. Catalytic Asymmetric Epoxidation of 2-Cyclopentenones (pages 1701–1706)

      Anna Lee, Corinna M. Reisinger and Benjamin List

      Version of Record online: 5 JUN 2012 | DOI: 10.1002/adsc.201200072

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    9. Unprecedented Selective Oxidation of Styrene Derivatives using a Supported Iron Oxide Nanocatalyst in Aqueous Medium (pages 1707–1711)

      Fatemeh Rajabi, Nafiseh Karimi, Mohammad Reza Saidi, Ana Primo, Rajender S. Varma and Rafael Luque

      Version of Record online: 5 JUN 2012 | DOI: 10.1002/adsc.201100630

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    10. Electrochemically Initiated Tandem and Sequential Conjugate Addition Processes: One-Pot Synthesis of Diverse Functionalized Isoindolinones (pages 1717–1724)

      Pasqualmorica Antico, Vito Capaccio, Antonia Di Mola, Antonio Massa and Laura Palombi

      Version of Record online: 5 JUN 2012 | DOI: 10.1002/adsc.201200065

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    11. One-Pot Cascade Reactions using Fructose-6-phosphate Aldolase: Efficient Synthesis of D-Arabinose 5-Phosphate, D-Fructose 6-Phosphate and Analogues (pages 1725–1730)

      Israel Sánchez-Moreno, Virgil Hélaine, Nicolas Poupard, Franck Charmantray, Bertrand Légeret, Laurence Hecquet, Eduardo García-Junceda, Roland Wohlgemuth, Christine Guérard-Hélaine and Marielle Lemaire

      Version of Record online: 5 JUN 2012 | DOI: 10.1002/adsc.201200150

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  5. Full Papers

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Review
    5. Communications
    6. Full Papers
    7. Updates
    8. Book Review
    1. The Substrate Spectrum of the Inverting sec-Alkylsulfatase Pisa1 (pages 1737–1742)

      Markus Schober, Tanja Knaus, Michael Toesch, Peter Macheroux, Ulrike Wagner and Kurt Faber

      Version of Record online: 5 JUN 2012 | DOI: 10.1002/adsc.201100864

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    2. Access to Enantiopure α-Alkyl-β-hydroxy Esters through Dynamic Kinetic Resolutions Employing Purified/Overexpressed Alcohol Dehydrogenases (pages 1743–1749)

      Aníbal Cuetos, Ana Rioz-Martínez, Fabricio R. Bisogno, Barbara Grischek, Iván Lavandera, Gonzalo de Gonzalo, Wolfgang Kroutil and Vicente Gotor

      Version of Record online: 29 MAY 2012 | DOI: 10.1002/adsc.201200139

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    3. Chemoenzymatic Synthesis of GDP-L-Fucose Derivatives as Potent and Selective α-1,3-Fucosyltransferase Inhibitors (pages 1750–1758)

      Yu-Nong Lin, Daniel Stein, Sheng-Wei Lin, Sue-Ming Chang, Ting-Chien Lin, Yu-Ruei Chuang, Jacquelyn Gervay-Hague, Hisashi Narimatsu and Chun-Hung Lin

      Version of Record online: 16 MAY 2012 | DOI: 10.1002/adsc.201100940

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    4. N-Octanoyldimethylglycine Trifluoroethyl Ester, an Acyl Donor Leading to Highly Enantioselective Protease-Catalysed Kinetic Resolution of Amines (pages 1759–1764)

      Severine Queyroy, Nicolas Vanthuyne, Stéphane Gastaldi, Michèle P. Bertrand and Gérard Gil

      Version of Record online: 5 JUN 2012 | DOI: 10.1002/adsc.201100993

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    5. Stereospecific Reduction of Methyl o-Chlorobenzoylformate at 300 g⋅L−1 without Additional Cofactor using a Carbonyl Reductase Mined from Candida glabrata (pages 1765–1772)

      Hongmin Ma, Linlin Yang, Yan Ni, Jie Zhang, Chun-Xiu Li, Gao-Wei Zheng, Huaiyu Yang and Jian-He Xu

      Version of Record online: 11 JUN 2012 | DOI: 10.1002/adsc.201100366

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    6. Evaluation of the Chiral DIANANE Backbone as Ligand for Organolithium Reagents (pages 1780–1790)

      Jezabel Praz, Laure Guénée, Sarwar Aziz, Albrecht Berkessel and Alexandre Alexakis

      Version of Record online: 11 JUN 2012 | DOI: 10.1002/adsc.201101016

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    7. Three-Step One-Pot Synthesis of Imidazo[2,1-b]chalcogenazoles via Intramolecular Cyclization of N-Alkynylimidazoles (pages 1791–1796)

      Juliano Alex Roehrs, Renan P. Pistoia, Davi F. Back and Gilson Zeni

      Version of Record online: 11 JUN 2012 | DOI: 10.1002/adsc.201200075

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    8. One-Pot Three-Component Click Reaction of Cyclic Sulfates and Cyclic Sulfamidates (pages 1797–1803)

      Alicia Megia-Fernandez, Mariano Ortega-Muñoz, Fernando Hernandez-Mateo and Francisco Santoyo-Gonzalez

      Version of Record online: 5 JUN 2012 | DOI: 10.1002/adsc.201100813

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  6. Updates

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Review
    5. Communications
    6. Full Papers
    7. Updates
    8. Book Review
    1. Asymmetric Homogeneous Hydrogenation in Flow using a Tube-in-Tube Reactor (pages 1805–1812)

      Sean Newton, Steven V. Ley, Eva Casas Arcé and Damian M. Grainger

      Version of Record online: 29 MAY 2012 | DOI: 10.1002/adsc.201200073

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    2. Transition Metal-Free Stereoselective α-Vinylation of Cyclic Ketones with Arylacetylenes in the Superbasic Catalytic Triad Potassium Hydroxide/tert-Butyl Alcohol/Dimethyl Sulfoxide (pages 1813–1818)

      Boris A. Trofimov, Elena Yu. Schmidt, Nadezhda V. Zorina, Elena V. Ivanova, Igor' A. Ushakov and Al'bina I. Mikhaleva

      Version of Record online: 5 JUN 2012 | DOI: 10.1002/adsc.201200210

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  7. Book Review

    1. Top of page
    2. Cover Picture
    3. Contents
    4. Review
    5. Communications
    6. Full Papers
    7. Updates
    8. Book Review
    1. Asymmetric Organocatalysis – Workbench Edition. Editors: Benjamin List and Keiji Maruoka (page 1833)

      Philipp Selig and Dieter Enders

      Version of Record online: 14 JUN 2012 | DOI: 10.1002/adsc.201200331

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      Georg Thieme Verlag: 2012. softcover, 2 Volumes, 1928 pp., € 449.00, US$ 549.00; ISBN 978-3-13-170591-4

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