Advanced Synthesis & Catalysis

Cover image for Vol. 355 Issue 7

May 3, 2013

Volume 355, Issue 7

Pages 1225–1432

  1. Cover Pictures

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Communications
    5. Full Papers
    6. Update
    1. You have free access to this content
      Cover Picture: (Adv. Synth. Catal. 7/2013) (page 1225)

      Version of Record online: 10 MAY 2013 | DOI: 10.1002/adsc.201390011

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      The cover picture, provided by De Miguel, Velado, Herradón and Mann, describes the process for the synthesis of functionalized bicyclic imines from readily available ω-azidodienes through a cascade reaction sequence. The transformation is highly selective and involves an intramolecularazide-alkene 1,3-dipolar cycloaddition, followed by an intramolecular Michael addition of the resulting five- or sixmembered ring cyclic enamines to different Michael acceptors (Stork alkylation), to afford the corresponding bicyclic imines in moderate to good yields. This methodology is illustrated in the communication by Mann and co-workers on pages 1237–1242.

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      Back Cover: (Adv. Synth. Catal. 7/2013) (page 1436)

      Version of Record online: 10 MAY 2013 | DOI: 10.1002/adsc.201390013

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      The cover picture, provided by Huang and co-workers, depicts a cooperative catalysis with aldehyde and copper for the aerobic oxidative C[BOND]H amination of azoles. The aldehyde acts as a catalyst to activate the amine to form aminal A, which then reacts with CuBr2 to generate the copper-amide B and regenerate the aldehyde to complete the aldehyde catalysis. Copper-amide B reacts with benzoxazole to generate organocopper B via C[BOND]H activation. Subsequent reductive elimination provides the desired product and releases Cu(I), which is oxidized by O2 to afford Cu(II) and complete the catalysis. This cooperative catalysis is illustrated in the full paper by Huang and co-workers on pages 1315--1322.

  2. Contents

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Communications
    5. Full Papers
    6. Update
    1. You have free access to this content
  3. Communications

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Communications
    5. Full Papers
    6. Update
    1. Catalytic Enantioselective Addition of Alkyl Grignard Reagents to Aliphatic Aldehydes (pages 1249–1254)

      Emilio Fernández-Mateos, Beatriz Maciá and Miguel Yus

      Version of Record online: 30 APR 2013 | DOI: 10.1002/adsc.201201117

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    2. Zheda-Phos for General α-Monoarylation of Acetone with Aryl Chlorides (pages 1255–1259)

      Pengbin Li, Bo Lü, Chunling Fu and Shengming Ma

      Version of Record online: 30 APR 2013 | DOI: 10.1002/adsc.201300207

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    3. A Copper-Catalyzed Aerobic Cascade Dehydrogenative– Dehalogenative Reaction (pages 1284–1290)

      Lei Liang, Guanyu Yang, Wei Wang, Fengrong Xu, Yan Niu, Qi Sun and Ping Xu

      Version of Record online: 30 APR 2013 | DOI: 10.1002/adsc.201300026

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    4. Asymmetric Rhodium-Catalyzed 1,4- and 1,2-Additions of Arylboronic Acids to Activated Ketones in Water at Room Temperature Using a Mixed Sulfur-Olefin Ligand (pages 1303–1307)

      Noureddine Khiar, Victoria Valdivia, Álvaro Salvador, Ahmed Chelouan, Ana Alcudia and Inmaculada Fernández

      Version of Record online: 30 APR 2013 | DOI: 10.1002/adsc.201201065

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  4. Full Papers

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Communications
    5. Full Papers
    6. Update
    1. Copper(I)-Catalyzed Coupling Cyclization of Methyl Perfluoroalk-2-ynoates with 2-Aminobenzonitriles: Synthesis of 2-Perfluoroalkylated Quinolines (pages 1345–1350)

      Jing Han, Long Cao, Linglin Bian, Jie Chen, Hongmei Deng, Min Shao, Zhijun Jin, Hui Zhang and Weiguo Cao

      Version of Record online: 9 APR 2013 | DOI: 10.1002/adsc.201201107

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    2. Phosphorus-Carbon Bond Formation: Palladium-Catalyzed Cross-Coupling of H-Phosphinates and Other P(O)H-Containing Compounds (pages 1361–1373)

      Olivier Berger, Christelle Petit, Eric L. Deal and Jean-Luc Montchamp

      Version of Record online: 30 APR 2013 | DOI: 10.1002/adsc.201300069

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    3. Rhodium-Catalyzed Asymmetric Cycloisomerization of 1,6-Ene-ynamides (pages 1374–1382)

      Takahiro Nishimura, Yuka Takiguchi, Yuko Maeda and Tamio Hayashi

      Version of Record online: 30 APR 2013 | DOI: 10.1002/adsc.201300148

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    4. On the Gold-Catalyzed Intramolecular 7-exo-trig Hydroamination of Allenes (pages 1383–1393)

      Daniel Pflästerer, Praphasiri Dolbundalchok, Shahid Rafique, Matthias Rudolph, Frank Rominger and A. Stephen K. Hashmi

      Version of Record online: 30 APR 2013 | DOI: 10.1002/adsc.201300154

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    5. Enantioselective Addition of Diphenylphosphine to 3-Methyl-4-nitro-5-alkenylisoxazoles (pages 1403–1408)

      Renta Jonathan Chew, Yinhua Huang, Yongxin Li, Sumod A. Pullarkat and Pak-Hing Leung

      Version of Record online: 30 APR 2013 | DOI: 10.1002/adsc.201300164

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    6. Synthesis of Functionalized trans-A2B2-Porphyrins Using Donor–Acceptor Cyclopropane-Derived Dipyrromethanes (pages 1409–1422)

      M. Hassan Beyzavi, Carolin Nietzold, Hans-Ulrich Reissig and Arno Wiehe

      Version of Record online: 30 APR 2013 | DOI: 10.1002/adsc.201300141

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  5. Update

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Communications
    5. Full Papers
    6. Update

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