Advanced Synthesis & Catalysis

Cover image for Vol. 356 Issue 10

July 7, 2014

Volume 356, Issue 10

Pages 2125–2354

  1. Cover Pictures

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Review
    6. Communications
    7. Full Papers
    8. Updates
    1. You have free access to this content
      Cover Picture: Nickel-Catalyzed Regio- and Stereoselective Reductive Coupling of Oxa- and Azabicyclic Alkenes with Enones and Electron-Rich Alkynes (Adv. Synth. Catal. 10/2014) (page 2125)

      Subramaniyan Mannathan and Chien-Hong Cheng

      Article first published online: 13 JUN 2014 | DOI: 10.1002/adsc.201400535

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      The front cover picture, provided by Chien-Hong Cheng, illustrates a highly regio- and stereoselective nickel-catalyzed reductive coupling reaction of oxa- and azabicyclic alkenes with enones and electron-rich alkynes. The reaction is highly atom economical affording cis-2- alkyl- and alkenyl-1,2-dihydronaphthalenes in good to excellent yields. Besides, 2-alkyl naphthalene derivatives also can be prepared under similar reaction conditions. The picture at the center is Department of Chemistry, National Tsing Hua University, in Hsinchu, Taiwan. Details can be found in the full paper on pages 2239–2246 (S. Mannathan and C.-H. Cheng, Adv. Synth. Catal. 2014, 356, 2239–2246 DOI: 10.1002/adsc.201300910).

    2. You have free access to this content
      Inside Cover Picture: Laccase/2,2,6,6-Tetramethylpiperidinoxyl Radical (TEMPO): An Efficient Catalytic System for Selective Oxidations of Primary Hydroxy and Amino Groups in Aqueous and Biphasic Media (Adv. Synth. Catal. 10/2014) (page 2126)

      Alba Díaz-Rodríguez, Lía Martínez-Montero, Iván Lavandera, Vicente Gotor and Vicente Gotor-Fernández

      Article first published online: 24 JUN 2014 | DOI: 10.1002/adsc.201400589

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      The inside cover picture, provided by Dbaz-Rodrbguez et al., illustrates the oxidization of alcohols, diols or amino alcohols in buffer solution under aerobic conditions using the laccase from Trametes versicolor together with 2,2,6,6-tetramethylpiperidinoxyl radical (TEMPO). This practical and efficient methodology promotes the chemoselective oxidation of hydroxy or amino groups, leading to aldehydes, lactones, hemiaminals or lactams in good yields. Addition of methyl tert-butyl ether allows the TEMPO loading to be reduced, also enhancing the solubility of hydrophobic compounds. Details of this work can be found in the Update on pages 2321–2329 (A. Dbaz-Rodrbguez, L. Martbnez-Montero, I. Lavandera, V. Gotor, V. Gotor- Fernndez, Adv. Synth. Catal. 2014, 356, 2321–2329; DOI: 10.1002/adsc.201400260).

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      Back Cover Picture: One-Pot Asymmetric Synthesis of Substituted Tetrahydrofurans via a Multicatalytic Benzoin/Michael/Acetalization Cascade (Adv. Synth. Catal. 10/2014) (page 2360)

      Gu He, Fengbo Wu, Wei Huang, Rui Zhou, Liang Ouyang and Bo Han

      Article first published online: 20 JUN 2014 | DOI: 10.1002/adsc.201400541

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      The back cover picture, showcases research from the groups of Bo Han and Gu He. A sequential benzoin/Michael/acetalization tandem reaction catalyzed by NHC and amine together has been developed to afford chiral tetrahydrofuran derivatives. The high yield and stereocontrol of this process may be due to both acid-promoted symmetrization of racemic acyloins and iminium ion activation of enals, as reported in the full paper on pages 2311–2319 (G. He, F.Wu,W. Huang, R. Zhou, L. Ouyang, and B. Han, Adv. Synth. Catal. 2014, 356, 2311–2319; DOI: 10.1002/adsc.201400172).

  2. Contents

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Review
    6. Communications
    7. Full Papers
    8. Updates
    1. Graphical Abstract: Adv. Synth. Catal. 10/2014 (pages 2127–2133)

      Article first published online: 2 JUL 2014 | DOI: 10.1002/adsc.201490008

  3. Corrigendum

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Review
    6. Communications
    7. Full Papers
    8. Updates
    1. You have free access to this content
  4. Review

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Review
    6. Communications
    7. Full Papers
    8. Updates
    1. Catalytic Isonitrile Insertions and Condensations Initiated by RNC–X Complexation (pages 2135–2196)

      Suravi Chakrabarty, Shruti Choudhary, Arpit Doshi, Fa-Qiang Liu, Rishabh Mohan, Manasa P. Ravindra, Dhruv Shah, Xun Yang and Fraser F. Fleming

      Article first published online: 20 JUN 2014 | DOI: 10.1002/adsc.201400017

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  5. Communications

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Review
    6. Communications
    7. Full Papers
    8. Updates
    1. One-Step C-Terminal Deprotection and Activation of Peptides with Peptide Amidase from Stenotrophomonas maltophilia in Neat Organic Solvent (pages 2197–2202)

      Muhammad I. Arif, Ana Toplak, Wiktor Szymanski, Ben L. Feringa, Timo Nuijens, Peter J. L. M. Quaedflieg, Bian Wu and Dick B. Janssen

      Article first published online: 20 JUN 2014 | DOI: 10.1002/adsc.201400109

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    2. Asymmetric Synthesis of α-Amino Acids under Operationally Convenient Conditions (pages 2203–2208)

      Manuel Jörres, Xia Chen, José Luis Aceña, Carina Merkens, Carsten Bolm, Hong Liu and Vadim A. Soloshonok

      Article first published online: 20 JUN 2014 | DOI: 10.1002/adsc.201400405

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    3. Chiral N,N′-Dioxide–Scandium(III)-Catalyzed Asymmetric Epoxidation of 2-Arylidene-1,3-diketones with Hydrogen Peroxide (pages 2214–2218)

      Yangyang Chu, Xiaoyu Hao, Lili Lin, Weiliang Chen, Wei Li, Fei Tan, Xiaohua Liu and Xiaoming Feng

      Article first published online: 20 JUN 2014 | DOI: 10.1002/adsc.201400341

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  6. Full Papers

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Review
    6. Communications
    7. Full Papers
    8. Updates
    1. Dynamic Kinetic Resolution of 2-Phenylpropanal Derivatives to Yield β-Chiral Primary Amines via Bioamination (pages 2257–2265)

      Christine S. Fuchs, Manuel Hollauf, Maximilian Meissner, Robert C. Simon, Tatiana Besset, Joost N. H. Reek, Waander Riethorst, Ferdinand Zepeck and Wolfgang Kroutil

      Article first published online: 4 JUN 2014 | DOI: 10.1002/adsc.201400217

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    2. Iminoxyl Radical-Based Strategy for Intermolecular C[BOND]O Bond Formation: Cross-Dehydrogenative Coupling of 1,3-Dicarbonyl Compounds with Oximes (pages 2266–2280)

      Igor B. Krylov, Alexander O. Terent'ev, Vladimir P. Timofeev, Boris N. Shelimov, Roman A. Novikov, Valentina M. Merkulova and Gennady I. Nikishin

      Article first published online: 20 JUN 2014 | DOI: 10.1002/adsc.201400143

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  7. Updates

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Review
    6. Communications
    7. Full Papers
    8. Updates
    1. Direct and Enantioselective Vinylogous Michael Addition of α-Alkylidenepyrazolinones to Nitroolefins Catalyzed by Dual Cinchona Alkaloid Thioureas (pages 2330–2336)

      Gloria Rassu, Vincenzo Zambrano, Luigi Pinna, Claudio Curti, Lucia Battistini, Andrea Sartori, Giorgio Pelosi, Giovanni Casiraghi and Franca Zanardi

      Article first published online: 28 MAY 2014 | DOI: 10.1002/adsc.201300964

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    2. One-Pot Sandmeyer Trifluoromethylation and Trifluoromethylthiolation (pages 2343–2348)

      Bilguun Bayarmagnai, Christian Matheis, Eugen Risto and Lukas J. Goossen

      Article first published online: 20 JUN 2014 | DOI: 10.1002/adsc.201400340

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