Advanced Synthesis & Catalysis

Cover image for Vol. 356 Issue 17

November 24, 2014

Volume 356, Issue 17

Pages 3473–3682

  1. Cover Pictures

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Review
    6. Communications
    7. Full Papers
    8. Updates
    1. You have free access to this content
      Cover Picture: Deracemization of Amino Acids by Coupling Transaminases of Opposite Stereoselectivity (Adv. Synth. Catal. 17/2014) (page 3473)

      Eul-Soo Park and Jong-Shik Shin

      Article first published online: 1 JUL 2014 | DOI: 10.1002/adsc.201400600

      Thumbnail image of graphical abstract

      The front cover picture, provided by Eul-Soo Park and Jong-Shik Shin, illustrates deracemization of amino acids by coupling transaminases of opposite stereoselectivity. The authors demonstrated that racemic amino acids could be converted into both enantiopure forms, depending on the stereoselectivity of the transaminases. Moreover, this strategy is free of H2O2 generation which is troublesome in oxidase-based methods. Details can be found in the communication on pages 3505–3509 (E.-S. Park, J.-S. Shin, Adv. Synth. Catal. 2014, 356, 3505–3509; DOI: 10.1002/adsc.201400185).

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      Inside Cover: The Synthesis of Highly Active Iridium(I) Complexes and their Application in Catalytic Hydrogen Isotope Exchange (Adv. Synth. Catal. 17/2014) (page 3474)

      Jack A. Brown, Alison R. Cochrane, Stephanie Irvine, William J. Kerr, Bhaskar Mondal, John A. Parkinson, Laura C. Paterson, Marc Reid, Tell Tuttle, Shalini Andersson and Göran N. Nilsson

      Article first published online: 18 NOV 2014 | DOI: 10.1002/adsc.201401054

      Thumbnail image of graphical abstract

      The inside cover picture, by Kerr and co-workers, depicts a series of robust, yet highly active Ir(I) complexes bearing specifically encumbered N-heterocyclic carbene and phosphine ligands. These complexes are extremely effective in hydrogen isotope exchange processes (with D or T), with low catalyst loadings, good levels of selectivity, and broad directing group applicability. The labelling of several complex drug molecules further highlights the catalysts utility. Mechanistic insight into the operation of these catalysts has also been provided by a combination of NMR and theoretical DFT studies. Details of this work can be found in the full paper on pages 3551–3562 (J. A. Brown, A. R. Cochrane, S. Irvine, W. J. Kerr, B. Mondal, J. A. Parkinson, L. C. Paterson, M. Reid, T. Tuttle, S. Andersson, G. N. Nilsson, Adv. Synth. Catal. 2014, 356, 3551–3562; DOI:10.1002/adsc.201400730).

  2. Contents

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Review
    6. Communications
    7. Full Papers
    8. Updates
    1. You have free access to this content
      Graphical Abstract: Adv. Synth. Catal. 17/2014 (pages 3475–3481)

      Article first published online: 18 NOV 2014 | DOI: 10.1002/adsc.201490013

  3. Corrigendum

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Review
    6. Communications
    7. Full Papers
    8. Updates
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      Corrigendum: Evaluating Thiourea Architecture for Intramolecular [2+2] Photocycloaddition of 4-Alkenylcoumarins (page 3481)

      Nandini Vallavoju, Sermadurai Selvakumar, Steffen Jockusch, Manoj Thathamkulam Prabhakaran, Mukund P. Sibi and Jayaraman Sivaguru

      Article first published online: 18 NOV 2014 | DOI: 10.1002/adsc.201400949

      This article corrects:

      Evaluating Thiourea Architecture for Intramolecular [2+2] Photocycloaddition of 4-Alkenylcoumarins

      Vol. 356, Issue 13, 2763–2768, Article first published online: 11 SEP 2014

  4. Review

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Review
    6. Communications
    7. Full Papers
    8. Updates
  5. Communications

    1. Top of page
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    3. Contents
    4. Corrigendum
    5. Review
    6. Communications
    7. Full Papers
    8. Updates
    1. A Palladium-Catalyzed Carbonylative–Deacetylative Sequence to 1,3-Keto Amides (pages 3519–3524)

      Dennis U. Nielsen, Signe Korsager, Anders T. Lindhardt and Troels Skrydstrup

      Article first published online: 5 NOV 2014 | DOI: 10.1002/adsc.201400545

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    2. Palladium-Catalyzed Hydroxymethylation of Aryl- and Heteroarylboronic Acids using Aqueous Formaldehyde (pages 3525–3529)

      Tetsuya Yamamoto, Azamat Zhumagazin, Takuma Furusawa, Ryoji Tanaka, Tetsu Yamakawa, Yohei Oe and Tetsuo Ohta

      Article first published online: 5 NOV 2014 | DOI: 10.1002/adsc.201400845

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    3. Enantioselective Protonation by Aza-Michael Reaction between Pyrazoles and α-Substituted Vinyl Ketones (pages 3545–3550)

      Jianlin Zhang, Yulong Zhang, Xiaohua Liu, Jing Guo, Weidi Cao, Lili Lin and Xiaoming Feng

      Article first published online: 16 OCT 2014 | DOI: 10.1002/adsc.201400616

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  6. Full Papers

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Review
    6. Communications
    7. Full Papers
    8. Updates
    1. The Synthesis of Highly Active Iridium(I) Complexes and their Application in Catalytic Hydrogen Isotope Exchange (pages 3551–3562)

      Jack A. Brown, Alison R. Cochrane, Stephanie Irvine, William J. Kerr, Bhaskar Mondal, John A. Parkinson, Laura C. Paterson, Marc Reid, Tell Tuttle, Shalini Andersson and Göran N. Nilsson

      Article first published online: 2 OCT 2014 | DOI: 10.1002/adsc.201400730

      Thumbnail image of graphical abstract
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  7. Updates

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Review
    6. Communications
    7. Full Papers
    8. Updates

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