Advanced Synthesis & Catalysis

Cover image for Vol. 356 Issue 18

December 15, 2014

Volume 356, Issue 18

Pages 3685–3915

  1. Cover Pictures

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Review
    6. Communications
    7. Full Papers
    8. Updates
    9. Book Review
    1. You have free access to this content
      Cover Picture: Continuous Synthesis of Organozinc Halides Coupled to Negishi Reactions (Adv. Synth. Catal. 18/2014) (page 3685)

      Nerea Alonso, L. Zane Miller, Juan de M. Muñoz, Jesus Alcázar and D. Tyler McQuade

      Article first published online: 7 NOV 2014 | DOI: 10.1002/adsc.201401043

      Thumbnail image of graphical abstract

      The front cover picture, provided by Tyler McQuade and co-authors, illustrates the continuous formation of organozinc halides suitable for use in downstream Negishi couplings. The approach combines an activated packed-bed of metallic zinc to form the organozinc halides and a downstream supported palladium packed-bed. The two column system starting with a 12 g column of zinc provides excellent yields of a wide range of Negishi cross-coupling products. Details can be found in the communication on pages 3737–3741 (N. Alonso, L. Z. Miller, J. de M. Muñoz, J. Alcázar, D. T. McQuade, Adv. Synth. Catal. 2014, 356, 3737–3741; DOI: 10.1002/adsc.201400243).

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      Inside Cover: Increasing the Reactivity of Amides towards Organometallic Reagents: An Overview (Adv. Synth. Catal. 18/2014) (page 3686)

      Vittorio Pace, Wolfgang Holzer and Berit Olofsson

      Article first published online: 2 DEC 2014 | DOI: 10.1002/adsc.201401093

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      The inside cover picture, provided by Vittorio Pace, Wolfgang Holzer, and Berit Olofsson, illustrates reactions of amides with organometallic reagents. The nucleophilic addition of carbon nucleophiles to amides would be an efficient approach to access ketones or amines, but the low electrophilicity of amides has made these transformations challenging for synthetic chemists. In recent years, several novel concepts have been developed where amides are transformed into highly electrophilic imidoyl triflate and iminium ions, N-alkoxyamides or thioamides. Addition of organometallics to these species chemoselectively delivers amines or ketones. Details of this work can be found in the review on pages 3697–3736 (V. Pace, W. Holzer, B. Olofsson, Adv. Synth. Catal. 2014, 356, 3697–3736; DOI: 10.1002/adsc.201400630).

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      Back Cover: Convenient Synthesis of (E)-5-Aryl(halo)methylenebicyclo- [2.2.2]oct-2-enes and -[2.2.1]hept-2-enes via Lewis Acid- Promoted Carbohalogenation of Cyclic 2,6-Enynols (Adv. Synth. Catal. 18/2014) (page 3920)

      Ming-Chang P. Yeh, Hsin-Hui Lin, Siou-Fu Kuo, Pei-Jie Chen and Jyun-Wei Hong

      Article first published online: 10 NOV 2014 | DOI: 10.1002/adsc.201401045

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      The back cover picture, provided by Ming-Chang P. Yeh and co-authors, illustrates an efficient synthesis of (E)-5-halomethylenebicyclo[2.2.2]oct-2-enes and -[2.2.1]hept-2-enes from the simple and inexpensive FeX3 (X=Cl or Br) and C-4 propargyl-tethered cyclic 2-enols under air at room temperature in minutes.The fluoro-analogs are available from the reaction of TBS-protected cyclic 2,6-enynols with BF3 ⋅ OEt2 under the similar reaction conditions. Details of this work can be found in the communication on pages 3816–3820 (M. C. P. Yeh, H. H. Lin, S. F. Kuo, P. J. Chen, J. W. Hong, Adv. Synth. Catal. 2014, 356, 3816–3820; DOI: 10.1002/adsc.201400671).

  2. Contents

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Review
    6. Communications
    7. Full Papers
    8. Updates
    9. Book Review
    1. You have free access to this content
      Graphical Abstract: Adv. Synth. Catal. 18/2014 (pages 3687–3694)

      Article first published online: 4 DEC 2014 | DOI: 10.1002/adsc.201490014

  3. Corrigendum

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Review
    6. Communications
    7. Full Papers
    8. Updates
    9. Book Review
    1. You have free access to this content
  4. Review

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Review
    6. Communications
    7. Full Papers
    8. Updates
    9. Book Review
  5. Communications

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Review
    6. Communications
    7. Full Papers
    8. Updates
    9. Book Review
    1. Continuous Synthesis of Organozinc Halides Coupled to Negishi Reactions (pages 3737–3741)

      Nerea Alonso, L. Zane Miller, Juan de M. Muñoz, Jesus Alcázar and D. Tyler McQuade

      Article first published online: 20 JUN 2014 | DOI: 10.1002/adsc.201400243

      Thumbnail image of graphical abstract
    2. Oxidative Gold Catalysis Meets Photochemistry – Synthesis of Benzo[a]fluorenones from Diynes (pages 3755–3760)

      Pascal Nösel, Setareh Moghimi, Christoph Hendrich, Marten Haupt, Matthias Rudolph, Frank Rominger and A. Stephen K. Hashmi

      Article first published online: 14 NOV 2014 | DOI: 10.1002/adsc.201400969

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    3. Enantioselective Fluorination of β-Ketoamides Catalyzed by Ar-BINMOL-derived Salan[BOND]Copper Complex (pages 3769–3776)

      Long-Sheng Zheng, Yun-Long Wei, Ke-Zhi Jiang, Yuan Deng, Zhan-Jiang Zheng and Li-Wen Xu

      Article first published online: 1 OCT 2014 | DOI: 10.1002/adsc.201400603

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    4. Palladium-Catalyzed Regioselective ortho-Acylation of Azoxybenzenes with Aldehyde Derivatives (pages 3789–3793)

      Meng Sun, Le-Kai Hou, Xiang-Xiang Chen, Xiao-Juan Yang, Wei Sun and Yu-Shi Zang

      Article first published online: 5 NOV 2014 | DOI: 10.1002/adsc.201400594

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  6. Full Papers

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Review
    6. Communications
    7. Full Papers
    8. Updates
    9. Book Review
    1. Zeo-Click Synthesis: Copper-Zeolite-Catalyzed Synthesis of Ynamides (pages 3842–3848)

      Hassina Harkat, Sophie Borghèse, Matteo De Nigris, Serguei Kiselev, Valérie Bénéteau and Patrick Pale

      Article first published online: 21 NOV 2014 | DOI: 10.1002/adsc.201400189

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  7. Updates

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Review
    6. Communications
    7. Full Papers
    8. Updates
    9. Book Review
    1. Tunable Brønsted Acidity-Dependent Alkylation and Alkenylation of Indoles (pages 3871–3880)

      Kaikai Wu, Ping Wu, Liandi Wang, Jiping Chen, Chenglin Sun and Zhengkun Yu

      Article first published online: 21 OCT 2014 | DOI: 10.1002/adsc.201400477

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  8. Book Review

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Review
    6. Communications
    7. Full Papers
    8. Updates
    9. Book Review
    1. You have free access to this content
      Copper-Mediated Cross-Coupling Reactions. Editors: Gwilherm Evano and Nicolas Blanchard (pages 3913–3915)

      Gerard van Koten

      Article first published online: 20 NOV 2014 | DOI: 10.1002/adsc.201400950

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      John Wiley & Sons, Inc., 2014, xxxv +784 pp, Hardcover, 24×16.5 cm, ISBN 978-1-118-06045-2, US $ 195.00, Online ISBN 978-1-118-690659, DOI: 10.1002/9781118690659

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