Advanced Synthesis & Catalysis

Cover image for Vol. 356 Issue 6

April 14, 2014

Volume 356, Issue 6

Pages 1125–1374

  1. Cover Pictures

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Reviews
    6. Communications
    7. Full Papers
    8. Updates
    1. You have free access to this content
      Cover Picture: Biomimetic Aerobic C[BOND]H Olefination of Cyclic Enaminones at Room Temperature: Development toward the Synthesis of 1,3,5-Trisubstituted Benzenes (Adv. Synth. Catal. 6/2014) (page 1125)

      Yi-Yun Yu and Gunda I. Georg

      Article first published online: 5 FEB 2014 | DOI: 10.1002/adsc.201400050

      Thumbnail image of graphical abstract

      The front cover picture, provided by Yi-Yun Yu and Gunda I. Georg, illustrates a novel synthesis of 1,3,5-trisubstituted benzenes from cyclic enaminones featuring a C[BOND]H functionalization and Diels-Alder tandem sequence. First, the enaminone dienes were constructed atom-economically by a dehydrogenative cross-olefination. This palladium-catalyzed biomimetic C[BOND]H coupling uses oxygen as the terminal oxidant and proceeds smoothly at room temperature. Then, the enaminone dienes underwent a Diels-Alder tandem reaction to furnish distinct 1,3,5-trisubstituted benzenes, including chalcones, with easily controllable symmetry. This new protocol provides an alternative pathway for arene functionalization. The details are disclosed in the Update by Yu and Georg on pages 1359–1369 (Y.-Y. Yu, G. I. Georg, Adv. Synth. Catal.­ 2014, 356, 1359–1369; DOI: 10.1002/adsc.201300904).

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      Back Cover Picture: Non-Covalent Immobilization of Rare Earth Heterobimetallic Frameworks and their Reactivity in an Asymmetric Michael Addition (Adv. Synth. Catal. 6/2014) (page 1380)

      Jerome R. Robinson, Jagjit Yadav, Xinyuan Fan, Gretchen R. Stanton, Eric J. Schelter, Miquel A. Pericàs and Patrick J. Walsh

      Article first published online: 1 APR 2014 | DOI: 10.1002/adsc.201400298

      Thumbnail image of graphical abstract

      The back cover picture, provided by Jerome Robinson, depicts a novel non-covalent binding strategy for Shibasakib's REMB framework {RE=rare earth metal; M=Li, Na, K; B=BINOLate; RE:M:B=1:3:3, [M3(sol)n][(BINOLate)3RE]} and its reactivity in an asymmetric Michael addition. Immobilization of heterobimetallic Lewis acid catalysts through covalent binding can be challenging. Non-covalent immobilization is attractive due to ease of preparation and potential for reversible binding. Furthermore, the ligand identity impacts enantioselectivity as reported in the full paper on pages 1243–1254 (J. R. Robinson, J. Yadav, X. Y. Fan, G. R. Stanton, E. J. Schelter, M. A. Pericàs, P. J. Walsh, Adv. Synth. Catal.­ 2014, 356, 1243–1254; DOI: 10.1002/adsc.201400087).

  2. Contents

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Reviews
    6. Communications
    7. Full Papers
    8. Updates
    1. Graphical Abstract: Adv. Synth. Catal. 6/2014 (pages 1127–1134)

      Article first published online: 11 APR 2014 | DOI: 10.1002/adsc.201490004

  3. Corrigendum

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Reviews
    6. Communications
    7. Full Papers
    8. Updates
    1. You have free access to this content
  4. Reviews

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Reviews
    6. Communications
    7. Full Papers
    8. Updates
  5. Communications

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Reviews
    6. Communications
    7. Full Papers
    8. Updates
    1. Manganese-Catalyzed and Promoted Reactions of H-Phosphinate Esters (pages 1199–1204)

      Henry C. Fisher, Olivier Berger, Fabien Gelat and Jean-Luc Montchamp

      Article first published online: 27 MAR 2014 | DOI: 10.1002/adsc.201301157

      Thumbnail image of graphical abstract
    2. Synthesis of Diverse Azolo[c]quinazolines by Palladium(II)- Catalyzed Aerobic Oxidative Insertion of Isocyanides (pages 1205–1209)

      Tjøstil Vlaar, Lisa Bensch, Jasper Kraakman, Christophe M. L. Vande Velde, Bert U. W. Maes, Romano V. A. Orru and Eelco Ruijter

      Article first published online: 20 MAR 2014 | DOI: 10.1002/adsc.201301129

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    3. Rhodium-Catalysed Tandem Hydroformylation/Arylation Reaction with Boronic Acids (pages 1223–1228)

      Ana R. Almeida, Roberto D. Dias, Carlos J. P. Monteiro, Artur R. Abreu, Pedro M. P. Gois, J. Carles Bayon and Mariette M. Pereira

      Article first published online: 18 MAR 2014 | DOI: 10.1002/adsc.201300968

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    4. Silver Triflate-Catalyzed Cyclization of 2-Amino-6-propargyl- amineazines Leading to Iminoimidazoazines (pages 1235–1241)

      Mourad Chioua, Abdelouahid Samadi, Elena Soriano, Lourdes Infantes and José Marco-Contelles

      Article first published online: 18 MAR 2014 | DOI: 10.1002/adsc.201300799

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  6. Full Papers

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Reviews
    6. Communications
    7. Full Papers
    8. Updates
    1. Non-Covalent Immobilization of Rare Earth Heterobimetallic Frameworks and their Reactivity in an Asymmetric Michael Addition (pages 1243–1254)

      Jerome R. Robinson, Jagjit Yadav, Xinyuan Fan, Gretchen R. Stanton, Eric J. Schelter, Miquel A. Pericàs and Patrick J. Walsh

      Article first published online: 2 APR 2014 | DOI: 10.1002/adsc.201400087

      Thumbnail image of graphical abstract
    2. An Intramolecular Pyranone Diels–Alder Cycloaddition Approach to Cannabinol (pages 1337–1342)

      Fangfang Fan, Jingjing Dong, Jinqian Wang, Lina Song, Chuanjun Song and Junbiao Chang

      Article first published online: 20 MAR 2014 | DOI: 10.1002/adsc.201301037

      Thumbnail image of graphical abstract
  7. Updates

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Reviews
    6. Communications
    7. Full Papers
    8. Updates
    1. Synthesis of Fused Cyclopentenones through Palladium-Catalyzed Cyclization of 2-Iodoaryl Allenols (pages 1370–1374)

      Benito Alcaide, Pedro Almendros, José M. Alonso, Israel Fernández and Saeed Khodabakhshi

      Article first published online: 2 APR 2014 | DOI: 10.1002/adsc.201301127

      Thumbnail image of graphical abstract

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