Advanced Synthesis & Catalysis

Cover image for Vol. 357 Issue 5

March 23, 2015

Volume 357, Issue 5

Pages 845–1078

  1. Cover Pictures

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Reviews
    6. Communications
    7. Full Papers
    8. Updates
    1. Cover Picture: Synthesis of 3-Aryl-1-trifluoromethyltetrahydroisoquinolines by Brønsted Acid-Catalyzed C(sp3)[BOND]H Bond Functionalization (Adv. Synth. Catal. 5/2015) (page 845)

      Keiji Mori, Nobuaki Umehara and Takahiko Akiyama

      Article first published online: 18 MAR 2015 | DOI: 10.1002/adsc.201500195

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      The front cover picture, provided by Takahiko Akiyama and co-workers, illustrates a concise route to 3-aryl-1-trifluoromethyltetrahydroisoquinolines by benzylic [1,5-hydride shift mediated C[BOND]H bond functionalization. The [1,5]-hydride shift of the benzylic C(sp3)[BOND]H bond to trifluoromethyl ketimine occurred smoothly to produce the target skeleton in good to excellent chemical yields. Whereas N-4-methoxyphenyl ketimines gave the cis-isomer predominantly, use of N[BOND]H ketimines changed the diastereoselectivity to furnish the trans-isomer stereoselectively. Details can be found in the communication on pages 901–906 (K. Mori, N. Umehara, T. Akiyama, Adv. Synth. Catal. 2015, 357, 901–906; DOI: 10.1002/adsc.201400775).

    2. Inside Cover: C[BOND]N Coupling of Indoles and Carbazoles with Aromatic Chlorides Catalyzed by a Single-Component NHC-Nickel(0) Precursor (Adv. Synth. Catal. 5/2015) (page 846)

      Silvia G. Rull, Juan F. Blandez, Manuel R. Fructos, Tomás R. Belderrain and M. Carmen Nicasio

      Article first published online: 18 MAR 2015 | DOI: 10.1002/adsc.201500196

      Thumbnail image of graphical abstract

      The inside cover picture, provided by T. R. Belderrain, M. C. Nicasio and co-workers, illustrates the first example of nickel-mediated N-(hetero)arylation of indoles and carbazoles with (hetero)aromatic chlorides, the least expensive of aryl halides. The reported procedure, based on the use of the Ni(0) complex [(IPr)Ni(styrene)2] as catalytic precursor, affords the products in good to high yields, in short reac tion times without the addition of an excess of the N-heterocycle carbene ligand. Details can be found in the communication on pages 907–911 (S. G. Rull, J. F. Blandez, M. R. Fructos, T. R. Belderrain, M. C. Nicasio, Adv. Synth. Catal. 2015, 357, 907–911; DOI: 10.1002/adsc.201500030).

  2. Contents

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Reviews
    6. Communications
    7. Full Papers
    8. Updates
  3. Corrigendum

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Reviews
    6. Communications
    7. Full Papers
    8. Updates
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  4. Reviews

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Reviews
    6. Communications
    7. Full Papers
    8. Updates
  5. Communications

    1. Top of page
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    3. Contents
    4. Corrigendum
    5. Reviews
    6. Communications
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    8. Updates
    1. Very Important Publication

    2. Light-Sensitive and Recoverable N-Heterocyclic Carbene Copper(I) Complex in Homogeneous Catalysis (pages 917–922)

      Guodong Zhang, Rui Lang, Wenlong Wang, Hui Lv, Liyuan Zhao, Chungu Xia and Fuwei Li

      Article first published online: 12 MAR 2015 | DOI: 10.1002/adsc.201401140

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    3. Copper-Catalyzed Direct Arylselenation of Anilines by C[BOND]H Bond Cleavage (pages 933–939)

      Vanessa G. Ricordi, Samuel Thurow, Filipe Penteado, Ricardo F. Schumacher, Gelson Perin, Eder J. Lenardão and Diego Alves

      Article first published online: 25 FEB 2015 | DOI: 10.1002/adsc.201400804

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    4. Strained Dehydrogenative Ring Closure of Phenylcarbazoles (pages 945–949)

      Alexander W. Jones, Marie-Laure Louillat-Habermeyer and Frederic W. Patureau

      Article first published online: 4 MAR 2015 | DOI: 10.1002/adsc.201401136

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  6. Full Papers

    1. Top of page
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    3. Contents
    4. Corrigendum
    5. Reviews
    6. Communications
    7. Full Papers
    8. Updates
    1. Gold(I)-Catalyzed Synthesis of Unsymmetrical Ethers Using Alcohols as Alkylating Reagents (pages 1029–1036)

      Yongxiang Liu, Xiaoyu Wang, Yanshi Wang, Chuan Du, Hui Shi, Shengfei Jin, Chongguo Jiang, Jianyong Xiao and Maosheng Cheng

      Article first published online: 13 MAR 2015 | DOI: 10.1002/adsc.201401097

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  7. Updates

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Corrigendum
    5. Reviews
    6. Communications
    7. Full Papers
    8. Updates

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