Advanced Synthesis & Catalysis

Cover image for Vol. 357 Issue 6

April 13, 2015

Volume 357, Issue 6

Pages 1081–1315

  1. Cover Pictures

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Review
    5. Communications
    6. Full Papers
    7. Updates
    1. You have free access to this content
      Cover Picture: Hypoiodite-Catalyzed Regioselective Oxidation of Alkenes: An Expeditious Access to Aldehydes in Aqueous Micellar Media (Adv. Synth. Catal. 6/2015) (page 1081)

      Peraka Swamy, Marri Mahender Reddy, Mameda Naresh, Macharla Arun Kumar, Kodumuri Srujana, Chevella Durgaiah and Nama Narender

      Article first published online: 8 JAN 2015 | DOI: 10.1002/adsc.201401130

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      The front cover picture, provided by Nama Narender and co-workers, illustrates a highly regioselective oxidation process for the synthesis of aldehydes from alkenes in aqueous micellar media. This novel metal-free catalytic system utilizes NH4I as a pre-catalyst and oxone as a terminal oxidant under mild conditions. The catalytic cycle starts with the in situ generation of hypoiodite species and involves the formation of co-iodo intermediate and deiodination-facilitated vicinal aryl group migration through a semipinacol rearrangement. Details can be found in the communication on pages 1125–1130 (P. Swamy, M. M. Reddy, M. Naresh, M. A. Kumar, K. Srujana, C. Durgaiah, N. Narender, Adv. Synth. Catal.­ 2015, 357, 1125–1130; DOI: 10.1002/adsc.201400986).

    2. You have free access to this content
      Inside Cover: Iridium-Catalyzed Intramolecular Enantioselective C[BOND]H Alkylation at the C-2 Position of N-Alkenylindoles (Adv. Synth. Catal. 6/2015) (page 1082)

      Takanori Shibata, Naoto Ryu and Hideaki Takano

      Article first published online: 2 APR 2015 | DOI: 10.1002/adsc.201500271

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      The inside cover picture, provided by Takanori Shibata and co-workers, illustrates the development of an intramolecular and enantioselective C-2 alkylation of N-alkenylindoles. A p-anisoyl group at the C-3 position of the indole operates as an efficient directing group, and the combination of a cationic iridium(I) complex and chiral diphosphine ligands achieves excellent enantioselectivity in the intramolecular C[BOND]H alkylation. Synthetically important N-fused tricyclic compounds containing the indole skeleton were prepared in high to excellent ee (up to 98% ee). Details can be found in the communication on pages 1131–1135 (T. Shibata, N. Ryu, H. Takano, Adv. Synth. Catal.­ 2015, 357, 1131–1135; DOI: 10.1002/adsc.201401163).

  2. Contents

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Review
    5. Communications
    6. Full Papers
    7. Updates
    1. You have free access to this content
  3. Review

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Review
    5. Communications
    6. Full Papers
    7. Updates
    1. Supported Catalysis in Continuous-Flow Microreactors (pages 1093–1123)

      Rajesh Munirathinam, Jurriaan Huskens and Willem Verboom

      Article first published online: 4 MAR 2015 | DOI: 10.1002/adsc.201401081

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  4. Communications

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Review
    5. Communications
    6. Full Papers
    7. Updates
    1. Very Important Publication: Hypoiodite-Catalyzed Regioselective Oxidation of Alkenes: An Expeditious Access to Aldehydes in Aqueous Micellar Media (pages 1125–1130)

      Peraka Swamy, Marri Mahender Reddy, Mameda Naresh, Macharla Arun Kumar, Kodumuri Srujana, Chevella Durgaiah and Nama Narender

      Article first published online: 23 DEC 2014 | DOI: 10.1002/adsc.201400986

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    2. Rhodium-Catalyzed Direct C7 Alkynylation of Indolines (pages 1149–1153)

      Ning Jin, Changduo Pan, Honglin Zhang, Pan Xu, Yixiang Cheng and Chengjian Zhu

      Article first published online: 6 MAR 2015 | DOI: 10.1002/adsc.201401007

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    3. Enantiopure Helical Ferrocene–Triazole–Quinone Triads: Synthesis and Properties (pages 1154–1160)

      Ana M. del Hoyo, Alfonso Latorre, Raúl Díaz, Antonio Urbano and M. Carmen Carreño

      Article first published online: 24 MAR 2015 | DOI: 10.1002/adsc.201400998

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    4. Nickel-Catalyzed C[BOND]S Bond Formation: Synthesis of Aryl Sulfides from Arylsulfonyl Hydrazides and Boronic Acids (pages 1181–1186)

      Rahul Singh, Bharat Kumar Allam, Neetu Singh, Kumkum Kumari, Satish Kumar Singh and Krishna Nand Singh

      Article first published online: 6 MAR 2015 | DOI: 10.1002/adsc.201400983

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  5. Full Papers

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Review
    5. Communications
    6. Full Papers
    7. Updates
    1. Palladium on Carbon-Catalyzed Aqueous Transformation of Primary Alcohols to Carboxylic Acids Based on Dehydrogenation under Mildly Reduced Pressure (pages 1205–1210)

      Yoshinari Sawama, Kosuke Morita, Shota Asai, Masami Kozawa, Shinsuke Tadokoro, Junichi Nakajima, Yasunari Monguchi and Hironao Sajiki

      Article first published online: 24 MAR 2015 | DOI: 10.1002/adsc.201401123

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    2. Rhodium-Catalyzed Decarbonylative Direct Olefination of Arenes with Vinyl Carboxylic Acids (pages 1229–1236)

      Ruiying Qiu, Lingjuan Zhang, Conghui Xu, Yixiao Pan, Hongze Pang, Lijin Xu and Huanrong Li

      Article first published online: 24 MAR 2015 | DOI: 10.1002/adsc.201401020

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    3. Synthesis of 2,6-Dihalogenated Purine Nucleosides by Thermostable Nucleoside Phosphorylases (pages 1237–1244)

      Xinrui Zhou, Kathleen Szeker, Lin-Yu Jiao, Martin Oestreich, Igor A. Mikhailopulo and Peter Neubauer

      Article first published online: 25 MAR 2015 | DOI: 10.1002/adsc.201400966

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    4. Bioinspired, Base- and Metal-Free, Mild Decarboxylative Aldol Activation of Malonic Acid Half Thioesters Under Phase-Transfer Reaction Conditions (pages 1245–1257)

      Sean P. Bew, G. Richard Stephenson, Jacques Rouden, Polly-Anna Ashford, Manuel Bourane, Agathe Charvet, Virginie M. D. Dalstein, Raphael Jauseau, G. D. Hiatt-Gipson and Luis A. Martinez-Lozano

      Article first published online: 25 MAR 2015 | DOI: 10.1002/adsc.201400915

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  6. Updates

    1. Top of page
    2. Cover Pictures
    3. Contents
    4. Review
    5. Communications
    6. Full Papers
    7. Updates
    1. Rhodium(III)-Catalyzed Selective C[BOND]H Cyanation of Indolines and Indoles with an Easily Accessible Cyano Source (pages 1293–1298)

      Neeraj Kumar Mishra, Taejoo Jeong, Satyasheel Sharma, Youngmi Shin, Sangil Han, Jihye Park, Joa Sub Oh, Jong Hwan Kwak, Young Hoon Jung and In Su Kim

      Article first published online: 24 MAR 2015 | DOI: 10.1002/adsc.201401152

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    2. Copper(I)-Catalyzed Dehydrogenative Amidation of Arenes Using Air as the Oxidant (pages 1311–1315)

      Gang Li, Chunqi Jia, Qingliang Chen, Kai Sun, Feng Zhao, Hankui Wu, Zhiyong Wang, Yunhe Lv and Xiaolan Chen

      Article first published online: 16 MAR 2015 | DOI: 10.1002/adsc.201400883

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