The inside cover picture, provided by Feng Li and co-workers, illustrates the direct synthesis of α-alkylated arylacetamides from arylacetonitriles and primary alcohols. In the presence of a rhodium complex [Rh(cod)Cl]2/triphenylphosphine/potassium hydroxide system, the desired α-alkylated arylacetamides were obtained in 74–92% yield under microwave conditions. The experimental results in this paper are in sharp contrast with previous reports, where the coupling of arylacetonitriles and primary alcohols produced the α-alkylated arylacetonitriles. Notably, this research shows the potential of developing completely atom-economical reactions that involve the hydrogen autotransfer (or hydrogen borrowing) process. Details can be found in the full paper on pages 1405–1415 (F. Li, X. Zou, N. Wang, Adv. Synth. Catal. 2015, 357, 1405–1415; DOI: 10.1002/adsc.201401013).