Advanced Synthesis & Catalysis

Cover image for Vol. 359 Issue 14

July 17, 2017

Volume 359, Issue 14

Pages 2337–2519

  1. Front Cover Picture

    1. Top of page
    2. Front Cover Picture
    3. Cover Pictures
    4. Communications
    5. Full Papers
    6. Updates
    1. You have free access to this content
      Front Cover Picture: cis-4-Alkoxydialkyl- and cis-4-Alkoxydiarylprolinol Organocatalysts: High Throughput Experimentation (HTE)-Based and Design of Experiments (DoE)-Guided Development of a Highly Enantioselective aza-Michael Addition of Cyclic Imides to α,β-Unsaturated Aldehydes (Adv. Synth. Catal. 14/2017) (page 2337)

      Ismael Arenas, Alessandro Ferrali, Carles Rodríguez-Escrich, Fernando Bravo and Miquel A. Pericàs

      Version of Record online: 29 MAY 2017 | DOI: 10.1002/adsc.201700610

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      The front cover picture, provided by Miquel A. Pericàs and Fernando Bravo, illustrates the powerful combination of High Throughput Experimentation (HTE, that significantly speeds up catalyst selection) and Design of Experiments (DoE, that uses the best candidate as a bait to fish out the optimal reaction conditions). This process is exemplified in the not well resolved addition of nitrogen nucleophiles to enals. Details can be found in the full paper on pages 2414–2424 (I. Arenas, A. Ferrali, C. Rodríguez-Escrich, F. Bravo, M. A. Pericàs, Adv. Synth. Catal. 2017, 359, 2414–2424; DOI: 10.1002/adsc.201700120).

  2. Cover Pictures

    1. Top of page
    2. Front Cover Picture
    3. Cover Pictures
    4. Communications
    5. Full Papers
    6. Updates
    1. You have free access to this content
      Cover Picture: Metal-Free Difluoromethylthiolation, Trifluoromethylthiolation, and Perfluoroalkylthiolation with Sodium Difluoromethane- sulfinate, Sodium Trifluoromethanesulfinate or Sodium Perfluoro- alkanesulfinate (Adv. Synth. Catal. 14/2017) (page 2338)

      Qiang Yan, Lvqi Jiang, Wenbin Yi, Qiran Liu and Wei Zhang

      Version of Record online: 20 JUN 2017 | DOI: 10.1002/adsc.201700705

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      The inside cover picture, provided by Qiang Yan, Lvqi Jiang, Wenbin Yi, Qiran Liu, and Wei Zhang illustrates a new method for direct difluoromethylthiolation using easy-to-handle HCF2SO2Na as a reagent in the present of (EtO)2P(O)H and TMSCl. HCF2S+ generated from this system undergoes electrophilic reactions with aromatic compounds including indoles, pyrroles, and activated benzenes. This method is also applicable for trifluoromethylthiolation with CF3SO2Na and perfluoroalkylthiolation with RfSO2Na. Reaction mechanisms for the metal-free electrophilic fluoroalkylthiolation reactions are also discussed. Details of this work can be found in the full paper on pages 2471–2480 (Q. Yan, L. Jiang, W. Yi, Q. Liu, W. Zhang, Adv. Synth. Catal. 2017, 359, 2471–2480; DOI: 10.1002/adsc.201700270).

  3. Communications

    1. Top of page
    2. Front Cover Picture
    3. Cover Pictures
    4. Communications
    5. Full Papers
    6. Updates
    1. Concise Synthesis of Spiro[indoline-3,2′-pyrrolidine] and 1-Azacarbazole Derivatives via Copper-Catalyzed Cyclization of Indoles (pages 2339–2344)

      Peng-Fei Wang, Chao Chen, Hui Chen, Li-Shuai Han, Liu Liu, Hongbin Sun, Xiaoan Wen and Qing-Long Xu

      Version of Record online: 5 JUL 2017 | DOI: 10.1002/adsc.201700073

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    2. Bichromatic Photosynthesis of Coumarins by UV Filter-Enabled Olefin Metathesis (pages 2352–2357)

      Or Eivgi, Revannath L. Sutar, Ofer Reany and N. Gabriel Lemcoff

      Version of Record online: 23 MAY 2017 | DOI: 10.1002/adsc.201700316

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    3. Dehydrogenation of Nitrogen Heterocycles Using Graphene Oxide as a Versatile Metal-Free Catalyst under Air (pages 2358–2363)

      Jingyu Zhang, Shiya Chen, Fangfang Chen, Wensheng Xu, Guo-Jun Deng and Hang Gong

      Version of Record online: 4 JUL 2017 | DOI: 10.1002/adsc.201700178

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    4. N-Heterocyclic Carbene-Catalyzed Mannich Reaction for the Synthesis of β-Amino Ketones: N,N-Dimethylformamide as Carbon Source (pages 2369–2374)

      Anitha Alanthadka, E. Sankari Devi, A. Tamil Selvi, Subbiah Nagarajan, Vellaisamy Sridharan and C. Uma Maheswari

      Version of Record online: 5 JUL 2017 | DOI: 10.1002/adsc.201700125

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    5. One-pot Synthesis of Oxindoles through C−H Alkylation and Intramolecular Cyclization of Azobenzenes with Internal Olefins (pages 2396–2401)

      Sang Hoon Han, Neeraj Kumar Mishra, Hyeim Jo, Yongguk Oh, Mijin Jeon, Saegun Kim, Woo Jung Kim, Jong Suk Lee, Hyung Sik Kim and In Su Kim

      Version of Record online: 8 MAY 2017 | DOI: 10.1002/adsc.201700147

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    6. Very Important Publication

      Palladium-Catalyzed Direct β-C−H Arylation of Ketones with Arylboronic Acids in Water (pages 2402–2406)

      Xiaoyun Hu, Xiaobo Yang, Xi-Jie Dai and Chao-Jun Li

      Version of Record online: 8 MAY 2017 | DOI: 10.1002/adsc.201700277

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    7. Palladium-Catalyzed Synthesis of Tetrasubstituted Olefins by Triple Domino Process (pages 2407–2413)

      Kanagaraj Naveen, Savariyappan Albert Nikson and Paramasivan Thirumalai Perumal

      Version of Record online: 10 MAY 2017 | DOI: 10.1002/adsc.201700169

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  4. Full Papers

    1. Top of page
    2. Front Cover Picture
    3. Cover Pictures
    4. Communications
    5. Full Papers
    6. Updates
    1. Very Important Publication

    2. Acyl Radical Addition onto Aza-Baylis–Hillman Adducts: A Stereocontrolled Access to 2,3,5-Trisubstituted Pyrrolidines (pages 2434–2441)

      Simon Grélaud, Jonathan Lusseau, Stéphane Massip and Yannick Landais

      Version of Record online: 8 JUN 2017 | DOI: 10.1002/adsc.201700362

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    3. Application of Dehydroabietic Acid in Palladium-Catalysed Enyne Cycloisomerisation (pages 2442–2447)

      Na Wu, Ruikun Li, Feihu Cui and Yingming Pan

      Version of Record online: 27 JUN 2017 | DOI: 10.1002/adsc.201700061

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    4. Palladium-Catalyzed Regioselective Direct Arylation of Benzofurazans at the C-4 Position (pages 2448–2456)

      Imane Idris, Fazia Derridj, Jean-François Soulé and Henri Doucet

      Version of Record online: 23 JUN 2017 | DOI: 10.1002/adsc.201700435

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  5. Updates

    1. Top of page
    2. Front Cover Picture
    3. Cover Pictures
    4. Communications
    5. Full Papers
    6. Updates
    1. Amine Activation: N-Arylamino Acid Amide Synthesis from Isothioureas and Amino Acids (pages 2481–2498)

      Yan-Ping Zhu, Pieter Mampuys, Sergey Sergeyev, Steven Ballet and Bert U. W. Maes

      Version of Record online: 14 JUN 2017 | DOI: 10.1002/adsc.201700134

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