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Formation of 1D Hierarchical Structures Composed of Ni3S2 Nanosheets on CNTs Backbone for Supercapacitors and Photocatalytic H2 Production

Authors

  • Ting Zhu,

    1. School of Chemical and Biomedical Engineering, Nanyang Technological University, 70 Nanyang Drive, Singapore 637457, Singapore
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  • Hao Bin Wu,

    1. School of Chemical and Biomedical Engineering, Nanyang Technological University, 70 Nanyang Drive, Singapore 637457, Singapore
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  • Yabo Wang,

    1. School of Chemical and Biomedical Engineering, Nanyang Technological University, 70 Nanyang Drive, Singapore 637457, Singapore
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  • Rong Xu,

    1. School of Chemical and Biomedical Engineering, Nanyang Technological University, 70 Nanyang Drive, Singapore 637457, Singapore
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  • Xiong Wen (David) Lou

    Corresponding author
    1. School of Chemical and Biomedical Engineering, Nanyang Technological University, 70 Nanyang Drive, Singapore 637457, Singapore
    • School of Chemical and Biomedical Engineering, Nanyang Technological University, 70 Nanyang Drive, Singapore 637457, Singapore.
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Abstract

One-dimensional (1D) hierarchical structures composed of Ni3S2 nanosheets grown on carbon nanotube (CNT) backbone (denoted as CNT@Ni3S2) are fabricated by a rational multi-step transformation route. The first step involves coating the CNT backbone with a layer of silica to form CNT@SiO2, which serves as the substrate for the growth of nickel silicate (NiSilicate) nanosheets in the second step to form CNT@SiO2@NiSilicate core-double shell 1D structures. Finally the as-formed CNT@SiO2@NiSilicate 1D structures are converted into CNT-supported Ni3S2 nanosheets via hydrothermal treatment in the presence of Na2S. Simultaneously the intermediate silica layer is eliminated during the hydrothermal treatment, leading to the formation of CNT@Ni3S2 nanostructures. Because of the unique hybrid nano-architecture, the as-prepared 1D hierarchical structure is shown to exhibit excellent performance in both supercapacitors and photocatalytic H2 production.

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