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Stretching operational life of trickle-bed filters by liquid-induced pulse flow



When dilute liquid suspensions contaminated with fine solids are treated in catalytic trickle-bed reactors, bed plugging develops and increases the resistance to two-phase flow until ultimate unit shutdown for bed substitution with pristine catalyst. The release of deposited fines, or the inhibition of fines deposition over some regions of the collector, is expected to alleviate the plugging if liquid flow shock or periodic operation policies are implemented. Current physical models linking gas–liquid phase flow to space–time evolution of fines deposition and release are unable to depict this new type of filtration in trickle beds. This work attempts to fill in this gap by developing a dynamic multiphase flow deep-bed filtration model. The model incorporates the physical effects of porosity and effective specific surface area changes as a result of fines deposition/release, gas and suspension inertial effects, and coupling effects between the filtration parameters and the interfacial momentum exchange force terms. The release of the fine particles from the collector surface was assumed to be induced by the colloidal forces in the case of Brownian particles or by the hydrodynamic forces in the case of non-Brownian particles. An important finding of the work was that for noncolloidal fines both induced pulsing and liquid flow shock operations conferred substantial improvements (measured in terms of reduction in specific deposit and pressure drop) in the mitigation of plugging in trickle-bed reactors. However, because of the highest critical shear stress for fines in the colloidal range, induced pulsing did not substantiate any practically useful effect. © 2005 American Institute of Chemical Engineers AIChE J, 2005