Separations: Materials, Devices, and Processes
You have free access to this content
Development of silica-gel-supported polyethylenimine sorbents for CO2 capture from flue gas
Article first published online: 17 NOV 2011
DOI: 10.1002/aic.12771
Copyright © 2011 American Institute of Chemical Engineers (AIChE)
Additional Information
How to Cite
Zhang, Z., Ma, X., Wang, D., Song, C. and Wang, Y. (2012), Development of silica-gel-supported polyethylenimine sorbents for CO2 capture from flue gas. AIChE J., 58: 2495–2502. doi: 10.1002/aic.12771
Publication History
- Issue published online: 5 JUL 2012
- Article first published online: 17 NOV 2011
- Accepted manuscript online: 12 SEP 2011 11:15AM EST
- Manuscript Revised: 9 SEP 2011
- Manuscript Received: 2 MAY 2011
Funded by
- U.S. Department of Energy, National Energy Technology Laboratory (NETL) through DOE Grants. Grant Number: DE-FE0000458
Literature Cited
- 1, , , , . Acceleration of global warming due to carbon-cycle feedbacks in a coupled climate model. Nature. 2000; 408: 184–187.
- 2, . Carbon-Constrained World by Rapid Commercialization of Carbon Capture and Sequestration. AIChE J. 2007; 53: 3022–3028.
- 3. Global challenges and strategies for control, conversion and utilization of CO2 for sustainable development involving energy, catalysis, adsorption and chemical processing. Catalysis Today. 2006; 115: 2–32.
- 4. Carbon capture and storage: How green can black be? Science. 2009; 325: 1647–1652.
- 5, . A Technical, economic, and environmental assessment of amine-based co2 capture technology for power plant greenhouse gas control. Environ Sci Technol. 2002; 36: 4467–4475.
- 6. Amine Scrubbing for CO2 Capture. Science. 2009; 325: 1652–1654.
- 7, . Modeling of CO2 capture by aqueous monoethanolamine. AIChE J. 2003; 49: 1676–1686.
- 8, , , , . Amine-modified SBA-12 mesoporous silica for carbon dioxide capture: Effect of amine basicity on sorption properties. Micropor Mesopor Mater. 2008; 116: 336–342.
- 9, , , , , , . Ethylenediamine-modified SBA-15 as regenerable CO2 sorbent. Ind Eng Chem Res. 2005; 44: 3099–3105.
- 10, , , . Carbon dioxide capture by diamine-grafted SBA-15: A combined fourier transform infrared and mass spectrometry study. Ind Eng Chem Res. 2005; 44: 3702–3708.
- 11, , , . Thermal and chemical stability of regenerable solid amine sorbent for CO2 capture. Energy Fuels. 2006; 20: 1514–1520.
- 12, , . Adsorption characteristics of carbon dioxide on organically functionalized SBA-15. Micropor Mesopor Mater. 2005; 84: 357–365.
- 13, , , . Stepwise growth of melamine-based dendrimers into mesopores and their CO2 adsorption properties. Micropor Mesopor Mater. 2008; 111: 536–543.
- 14, , , , , , . Functionalised micro-/mesoporous silica for the adsorption of carbon dioxide. Micropor Mesopor Mater. 2007; 99: 79–85.
- 15, , , , , . Adsorption of carbon dioxide on organically functionalized SBA-16. Microporous Mesoporous Mater. 2008; 116: 394–399.
- 16, ; . New Insights into the Interactions of CO2 with Amine-Functionalized Silica. Ind Eng Chem Res. 2008; 47: 9406–9412.
- 17, , , . Tailoring Pore Properties of MCM-48 Silica for Selective Adsorption of CO2. J Phys Chem B. 2005; 109: 6287–6293.
- 18, , . Adsorptive removal of carbon dioxide using polyethyleneimine-loaded mesoporous silica materials. Micropor Mesopor Mater. 2008; 113: 31–40.
- 19, , , , . CO2 Capture by As-Prepared SBA-15 with an Occluded Organic Template. Adv Funct Mater. 2006; 16: 1717–1722.
- 20, , , , , , . Promoting the CO2 adsorption in the amine-containing SBA-15 by hydroxyl group. Microporous Mesoporous Mater. 2008; 114: 74–81.
- 21, , . “Molecular basket” sorbents for separation of CO2 and H2S from various gas streams. J Am Chem Soc. 2009; 131: 5777–5783.
- 22, , , , . Novel polyethylenimine-modified mesoporous molecular sieve of MCM-41 type as high-capacity adsorbent for CO2 capture. Energy Fuels. 2002; 16: 1463–1469.
- 23, , , . Influence of moisture on co2 separation from gas mixture by a nanoporous adsorbent based on polyethylenimine-modified molecular sieve MCM-41. Ind Eng Chem Res. 2005; 44: 8113–8119.
- 24, , , . Adsorption separation of carbon dioxide from flue gas of natural gas-fired boiler by a novel nanoporous “molecular basket” adsorbent. Fuel Process Technol. 2005; 86: 1457–1472.
- 25, , , , . Preparation and characterization of novel CO2 “molecular basket” adsorbents based on polymer-modified mesoporous molecular sieve MCM-41. Micropor Mesopor Mater. 2003; 62: 29–45.
- 26, , . Applications of pore-expanded mesoporous silica. 27. Development of a high-capacity, water-tolerant adsorbent for CO2. Ind Eng Chem Res. 2005; 44: 8007–8013.
- 28, , , , , . Efficient CO2 capturer derived from as-synthesized MCM-41 modified with amine. Chem Europ J. 2008; 14: 3442–3451.
- 29, , , . Mesoporous-molecular-sieve-supported Polymer Sorbents for Removing H2S from Hydrogen Gas Streams. Top Catal. 2008; 49: 108–117.
- 30, , , , , , . Infrared study of CO2 sorption over “molecular basket” sorbent consisting of polyethylenimine-modified mesoporous molecular sieve. J Phys Chem C. 2009; 113: 7260–7268.
- 31, , , , . Hydrothermal stability of mesoporous molecular sieve synthesized from fluorosilicon compound. J Ind Chem. 1999; 5: 245–252.
- 32, , , , , . Monoethanol amine modified zeolite 13X for CO2 adsorption at different temperatures. Energy Fuels. 2007; 21: 3555–3559.
- 33, , , , , . CO2 capture by polyethylenimine-modified fibrous adsorbent. Langmuir. 2008; 24: 6567–6574.
- 34, , , , , . Preparation and adsorption properties of polyethylenimine containing fibrous adsorbent for carbon dioxide capture. J Appl Polym Sci. 2008; 108: 3851–3858.
- 35, , , , . CO2 capture by adsorption with nitrogen enriched carbons. Fuel. 2007; 86: 2204–2212.
- 36, , , . High-capacity and low-cost carbon-based “molecular basket” sorbent for CO2 capture from flue gas. Energy Fuels. 2011; 25: 456–458.
- 37, , , . Adsorption of carbon dioxide using polyethyleneimine modified silica gel. Korean J Chem Eng. 2010; 27: 1910–1915.

1547-5905/asset/AIC_left.gif?v=1&s=43a3d567c64d3d5d712c0af6c2cacb1e1bcc1a2b)
1547-5905/asset/AIC_right.gif?v=1&s=518efadeedca9ceeef271499f690fdebd2ed9164)
