Catalytic hydrogenation of cyclohexene: Part II. Liquid phase reaction on supported platinum in a gradientless slurry reactor

Authors

  • R. J. Madon,

    1. Department of Chemical Engineering, Stanford University, Stanford, California 94305
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  • J. P. O'Connell,

    1. Department of Chemical Engineering, Stanford University, Stanford, California 94305
    Current affiliation:
    1. University of Florida, Gainesville, Florida 32611
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  • Michel Boudart

    Corresponding author
    1. Department of Chemical Engineering, Stanford University, Stanford, California 94305
    • Department of Chemical Engineering, Stanford University, Stanford, California 94305
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Abstract

The areal rate of liquid phase hydrogenation of cyclohexene on supported platinum catalysts does not depend on the nature of the support. Nor does it depend on particle size of the metal. The rate constant is independent of the nature of the solvent when the concentration of hydrogen in it is expressed as its measured or calculated solubility. All observations are compatible with the idea that the measured rate is that of chemisorption of dihydrogen on a metal surface covered with reactive hydrocarbon intermediates.

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