Get access

NMR Measurements of chemical theory equilibrium constants for hydrogen-bonded solutions



Although various chemical theories have often been used to characterize hydrogen-bonded systems with some success, they have been limited by the fact that the equilibrium constants were adjustable parameters. This paper reports a method to measure directly these constants by proton nuclear magnetic resonance spectroscopy. Results are reported for several systems and are used with a chemical-physical theory to predict vapor-liquid equilibria.

Get access to the full text of this article