Get access

Four-Step Reduction of dpp-bian with Sodium Metal: Crystal Structures of the Sodium Salts of the Mono-, Di-, Tri- and Tetraanions of dpp-bian

Authors

  • Igor L. Fedushkin Dr.,

    1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Tropinina 49, 603950 Nizhny Novgorod GSP-445, Russia, Fax: (+7) 8312-661-497
    Search for more papers by this author
  • Alexandra A. Skatova Dr.,

    1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Tropinina 49, 603950 Nizhny Novgorod GSP-445, Russia, Fax: (+7) 8312-661-497
    Search for more papers by this author
  • Valentina A. Chudakova Dr.,

    1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Tropinina 49, 603950 Nizhny Novgorod GSP-445, Russia, Fax: (+7) 8312-661-497
    Search for more papers by this author
  • Georgy K. Fukin Dr.

    1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Tropinina 49, 603950 Nizhny Novgorod GSP-445, Russia, Fax: (+7) 8312-661-497
    Search for more papers by this author

  • This work was supported by the Russian Foundation for Basic Research (Grant No. 03-03-32246à), dpp-bian=bis[N-(2,6-diisopropylphenyl)imino]acenaphthene

Abstract

original image

Vier anionische Formen des Liganden Bis[N-(2,6-diisopropylphenyl)imino]acenaphthen (dpp-bian) wurden durch Reduktion mit Natrium in Diethylether in präparativem Maßstab erhalten. Die Natriumsalze des Mono-, Di-, Tri- und Tetraanions (siehe Bild) wurden durch Einkristall-Röntgenstrukturanalyse eindeutig charakterisiert.

Get access to the full text of this article

Ancillary