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Activation of C[BOND]Cl and C[BOND]H Bonds by Ligated S22− Ions: Conversion of Organic Chlorides into Organosulfur Compounds in cis-[(IrCp*)2(μ-CH2)2(μ-S2R)]+

Authors

  • Tarlok Singh Lobana Prof. Dr.,

    1. Department of Materials Science, Graduate School of Science, Osaka City University, Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan, Fax: (+81) 76-264-5742
    2. Current address: Department of Chemistry, Guru Nanak Dev University, Amritsar—143 005, India, Fax: (+91) 183-2-258820
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  • Kiyoshi Isobe Prof. Dr.,

    1. Department of Materials Science, Graduate School of Science, Osaka City University, Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan, Fax: (+81) 76-264-5742
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  • Hiroaki Kitayama,

    1. Department of Materials Science, Graduate School of Science, Osaka City University, Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan, Fax: (+81) 76-264-5742
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  • Takanori Nishioka Dr.,

    1. Department of Materials Science, Graduate School of Science, Osaka City University, Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan, Fax: (+81) 76-264-5742
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  • Isamu Kinoshita Dr.

    1. Department of Materials Science, Graduate School of Science, Osaka City University, Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan, Fax: (+81) 76-264-5742
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  • We gladly acknowledge the award of an Invitation Fellowship for Professor Lobana from the Japan Society for the Promotion of Science(JSPS) and sabbatical leave by the parent university in Amritsar. Cp*=C5Me5.

Abstract

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Entgiftung mit Schwefel: C-Cl-Bindungen toxischer, polychlorierter organischer Verbindungen können durch den S2-Liganden des Komplexes 1 aktiviert werden. So entsteht bei der Reaktion von 1 mit C6H5CHCl2 oder C6H5CCl3 in Methanol ein Dithiobenzoat-Komplex, welcher durch Addition von NaBPh4 in den Komplex 2 übergeht (Cp*=C5Me5).

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