Get access

Excited-State Deprotonation and H/D Exchange of an Iridium Hydride Complex

Authors

  • Tomoyoshi Suenobu Dr.,

    1. Department of Material and Life Science, Graduate School of Engineering, Osaka University, CREST, Japan Science and Technology Corporation, 2-1 Yamada-oka Suita Osaka 565-0871, Japan, Fax: (+81) 6-6879-7370
    Search for more papers by this author
  • Dirk M. Guldi Prof. Dr.,

    1. Radiation Laboratory, University of Notre Dame, Notre Dame, Indiana 46556, USA, Fax: (+1) 574-631-8068
    Search for more papers by this author
  • Seiji Ogo Dr.,

    1. Department of Material and Life Science, Graduate School of Engineering, Osaka University, CREST, Japan Science and Technology Corporation, 2-1 Yamada-oka Suita Osaka 565-0871, Japan, Fax: (+81) 6-6879-7370
    Search for more papers by this author
  • Shunichi Fukuzumi Prof. Dr.

    1. Department of Material and Life Science, Graduate School of Engineering, Osaka University, CREST, Japan Science and Technology Corporation, 2-1 Yamada-oka Suita Osaka 565-0871, Japan, Fax: (+81) 6-6879-7370
    Search for more papers by this author

  • This work was partially supported by Grants-in-Aid for Scientific Research on Priority Area (Nos. 13555247 and 14045249) from the Ministry of Education, Culture, Sports, Science and Technology, Japan, and the offices of Basic Energy Sciences of the US Department of Energy (contribution no. NDRL-4481 from the Notre Dame radiation laboratory. The authors thank the reviewers for their useful comments and suggestions.

Abstract

original image

Laserpulsbestrahlung des Hexafluorophosphatsalzes von [Cp*IrIII(bpy)H]+ (1; Cp*=η5-C5Me5, bpy=2,2′-Bipyridin) führt zur Deprotonierung im angeregten Zustand und liefert die konjugierte Base [Cp*IrI(bpy)]. Der H-D-Austausch von 1 erfolgt auch bei kontinuierlicher Bestrahlung von 1 in [D4]Methanol (siehe Bild).

Ancillary