We would like to thank Professor Barry M. Trost (Stanford University) for helpful discussions. We also thank Dr. Shouquan Huo for performing initial hydrogenation experiments with ketone 5 a and for observing that the Ru/bicp/3 a-catalyzed hydrogenation of 5 a gave opposite enantiomers of the product 6 a when the solvent was changed from MeOH to EtOH. The pioneering work of Dr. Charles Tucker and Dr. Qiongzhong Jiang with bicp for the reduction of ketones is gratefully acknowledged. bicp=2,2′-bis(diphenylphosphanyl)-1,1′-dicyclopentane.
Asymmetric Hydrogenation of Ketones Catalyzed by RuII–bicp Complexes†
Article first published online: 12 MAY 2004
Copyright © 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Volume 116, Issue 21, pages 2876–2879, May 17, 2004
How to Cite
Genov, D. G. and Ager, D. J. (2004), Asymmetric Hydrogenation of Ketones Catalyzed by RuII–bicp Complexes. Angew. Chem., 116: 2876–2879. doi: 10.1002/ange.200353441
- Issue published online: 12 MAY 2004
- Article first published online: 12 MAY 2004
- Manuscript Received: 2 DEC 2003
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