Get access

Nitrido Ruthenium Porphyrins: Synthesis, Characterization, and Amination Reactions with Hydrocarbon or Silyl Enol Ethers

Authors

  • Sarana Ka-Yan Leung,

    1. Department of Chemistry and Open Laboratory of Chemical Biology of the Institute of Molecular Technology for Drug Discovery and Synthesis The University of Hong Kong, Pokfulam Road, Hong Kong, Fax: (+852) 2857-1586
    Search for more papers by this author
  • Jie-Sheng Huang Dr.,

    1. Department of Chemistry and Open Laboratory of Chemical Biology of the Institute of Molecular Technology for Drug Discovery and Synthesis The University of Hong Kong, Pokfulam Road, Hong Kong, Fax: (+852) 2857-1586
    Search for more papers by this author
  • Jiang-Lin Liang,

    1. Department of Chemistry and Open Laboratory of Chemical Biology of the Institute of Molecular Technology for Drug Discovery and Synthesis The University of Hong Kong, Pokfulam Road, Hong Kong, Fax: (+852) 2857-1586
    Search for more papers by this author
  • Chi-Ming Che Prof. Dr.,

    1. Department of Chemistry and Open Laboratory of Chemical Biology of the Institute of Molecular Technology for Drug Discovery and Synthesis The University of Hong Kong, Pokfulam Road, Hong Kong, Fax: (+852) 2857-1586
    Search for more papers by this author
  • Zhong-Yuan Zhou Prof.

    1. Department of Applied Biology and Chemical Technology The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong
    Search for more papers by this author

  • This work was supported by The University of Hong Kong, the Hong Kong University Foundation, the Hong Kong Research Grants Council, and the University Grants Committee of the Hong Kong SAR of China (Area of Excellence Scheme, AoE/P-10/01).

Abstract

original image

Eine bisher unbekannte Synthesestrategie wurde für die Herstellung von Nitridoruthenium(IV)-Porphyrinen wie 1 angewendet. Im Kristall hat die Ru-N(Nitrido)-Bindung eine Länge von 1.656(5) Å. Bei der Reaktion von Nitridoruthenium-Porphyrinen mit Silylenolethern oder Indan erhält man in Gegenwart von Trifluoressigsäureanhydrid N-Trifluoracetylamine in Ausbeuten von bis zu 84 %.

Ancillary