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Potent, Versatile, and Stable: Thiazolyl Thioglycosides as Glycosyl Donors

Authors

  • Alexei V. Demchenko Prof. Dr.,

    1. Department of Chemistry and Biochemistry, University of Missouri–St. Louis, 8001 Natural Bridge Road, St. Louis, MS 63121, USA, Fax: (+1) 314-516-5342
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  • Papapida Pornsuriyasak,

    1. Department of Chemistry and Biochemistry, University of Missouri–St. Louis, 8001 Natural Bridge Road, St. Louis, MS 63121, USA, Fax: (+1) 314-516-5342
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  • Cristina De Meo Dr.,

    1. Department of Chemistry and Biochemistry, University of Missouri–St. Louis, 8001 Natural Bridge Road, St. Louis, MS 63121, USA, Fax: (+1) 314-516-5342
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  • Nelli N. Malysheva Dr.

    1. Department of Chemistry and Biochemistry, University of Missouri–St. Louis, 8001 Natural Bridge Road, St. Louis, MS 63121, USA, Fax: (+1) 314-516-5342
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  • This work was supported by the University of Missouri Research Board and “The Foundation BLANCEFLOR Boncompagni-Ludovisi, née Bildt”.

Abstract

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1,2-trans- und 1,2-cis-Glycoside konnten mithilfe von Thiazolyl(Taz)-substituierten Thioglycosiden erhalten werden. Des Weiteren eignen sich diese Reagentien für die konvergente Oligosaccharidsynthese. Es konnte gezeigt werden, dass STaz- und SEt-Einheiten vollständig orthogonal sind (siehe Schema, Bn=Benzyl; X=STaz, Y=SEt oder X=SEt, Y=STaz).

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