Zuschrift

Dihydrogen Trioxide (HOOOH) Is Generated during the Thermal Reaction between Hydrogen Peroxide and Ozone†

  1. Paul T. Nyffeler1,
  2. Nicholas A. Boyle Dr.1,
  3. Laxman Eltepu Dr.1,
  4. Chi-Huey Wong Prof.1,
  5. Albert Eschenmoser Prof.3,
  6. Richard A. Lerner Prof.1,
  7. Paul Wentworth Jr. Prof.1,2

Article first published online: 12 AUG 2004

DOI: 10.1002/ange.200460457

Issue

Angewandte Chemie

Angewandte Chemie

Volume 116, Issue 35, pages 4756–4759, September 6, 2004

Additional Information

How to Cite

Nyffeler, P. T., Boyle, N. A., Eltepu, L., Wong, C.-H., Eschenmoser, A., Lerner, R. A. and Wentworth, P. (2004), Dihydrogen Trioxide (HOOOH) Is Generated during the Thermal Reaction between Hydrogen Peroxide and Ozone. Angewandte Chemie, 116: 4756–4759. doi: 10.1002/ange.200460457

Author Information

  1. 1

    Department of Chemistry & The Skaggs Institute for Chemical Biology, The Scripps Research Institute, 10550 N. Torrey Pines Rd., La Jolla, CA92037, USA, Fax: (+1) 858-784-2590

  2. 2

    Oxford Glycobiology Institute, Department of Biochemistry, University of Oxford, South Parks Rd., Oxford, OX1 3QU, UK

  3. 3

    Laboratorium für organische Chemie, Eidgenössische Technische Hochschule (ETH), Hönggerberg HCl-H309, Universitaetstrasse 16 8093 Zürich, Switzerland

  1. †

    This work was supported by the Skaggs Institute for Chemical Biology. P.W. thanks the members of The Scripps Research Institute NMR facility, especially Dr. D. Huang and Dr. L. Pasternack, for expert assistance during this study.

Publication History

  1. Issue published online: 31 AUG 2004
  2. Article first published online: 12 AUG 2004
  3. Manuscript Received: 26 APR 2004

SEARCH

SEARCH BY CITATION

ARTICLE TOOLS

View Full Article with Supporting Information (HTML) Get PDF (142K)

Keywords:

  • Deuterium;
  • Festphasensynthese;
  • Oxidationen;
  • Ozon;
  • Wasserstoffperoxid

Graphical Abstract

Thumbnail image of graphical abstract

Quantifizierbare Mengen an HOOOH werden durch 1H-NMR-spektroskopische Analyse der thermischen Reaktion von O3 mit HOOH detektiert (siehe Schema). Der erstmalige experimentelle Nachweis von HOOOH lässt darauf schließen, dass diese Spezies an Oxidationsreaktionen in biologischen, atmosphärischen und Umweltprozessen beteiligt ist.

View Full Article with Supporting Information (HTML) Get PDF (142K)