Difluoromethyl Phenyl Sulfone, a Difluoromethylidene Equivalent: Use in the Synthesis of 1,1-Difluoro-1-alkenes

Authors

  • G. K. Surya Prakash Prof. Dr.,

    1. Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA 90089-1661, USA, Fax: (+1) 213-740-6270
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  • Jinbo Hu Dr.,

    1. Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA 90089-1661, USA, Fax: (+1) 213-740-6270
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  • Ying Wang,

    1. Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA 90089-1661, USA, Fax: (+1) 213-740-6270
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  • George A. Olah Prof. Dr.

    1. Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA 90089-1661, USA, Fax: (+1) 213-740-6270
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  • Support of our work by Loker Hydrocarbon Research Institute is gratefully acknowledged.

Abstract

original image

Durch nucleophile Substitution und anschließende Eliminierung mit Difluormethyl(phenyl)sulfon als selektivem Difluormethyliden-Äquivalent gelang die einfache Synthese von 1,1-Difluor-1-alkenen aus primären Alkylhalogeniden (siehe Schema).

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