Palladium(0)-Catalyzed Hydroalkoxylation of Hexafluoropropene: Synthesis of Hydrofluoroethers under Neutral Conditions

Authors

  • Yasuhisa Matsukawa Dr.,

    1. Research Institute for Sustainable Chemical Innovation, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan, Fax: (+81) 29-861-4771
    Search for more papers by this author
  • Junji Mizukado Dr.,

    1. Research Institute for Sustainable Chemical Innovation, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan, Fax: (+81) 29-861-4771
    Search for more papers by this author
  • Heng-dao Quan Dr.,

    1. Research Institute for Sustainable Chemical Innovation, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan, Fax: (+81) 29-861-4771
    Search for more papers by this author
  • Masanori Tamura Dr.,

    1. Research Institute for Sustainable Chemical Innovation, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan, Fax: (+81) 29-861-4771
    Search for more papers by this author
  • Akira Sekiya Dr.

    1. Research Institute for Sustainable Chemical Innovation, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan, Fax: (+81) 29-861-4771
    Search for more papers by this author

  • This research was supported by the New Energy and Industrial Technology Development Organization (NEDO)

Abstract

original image

Ohne Bildung von Vinylethern als Nebenprodukten gelingt die Palladium(0)-katalysierte Hydroalkoxylierung von Hexafluorpropen (siehe Schema). In Gegenwart von [Pd(PPh3)4]/dppb führen die Reaktionen mit Alkoholen oder Phenolen unter neutralen Bedingungen selektiv zu den gesättigten Hydrofluorethern. dppb=1,4-Bis(diphenylphosphanyl)butan.

Ancillary