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Effect of the Metal-Assisted Assembling Mode on the Redox States of Hexaazatriphenylene Hexacarbonitrile

Authors

  • Shuhei Furukawa,

    1. Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732
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  • Takashi Okubo Dr.,

    1. School of Materials Science, Japan Advanced Institute of Science and Technology (JAIST), Asahidai, Tatsunokuchi, Ishikawa 923-1292, Japan
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  • Shigeyuki Masaoka Dr.,

    1. Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732
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  • Daisuke Tanaka,

    1. Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732
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  • Ho-Chol Chang Dr.,

    1. Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732
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  • Susumu Kitagawa Prof. Dr.

    1. Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2732
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  • We would like to thank Prof. Dr. Takashi Kawamura and Dr. Ryo Kitaura for their help with the DFT calculations. This work was supported by a Grant-In-Aid for Science Research from the Ministry of Education, Culture, Sports, Science and Technology, Japan. S.F. is grateful to the JSPS Research Fellowships for Young Scientists.

Abstract

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Die Größe der Ferrocen-Coliganden entscheidet bei der Selbstorganisation von Hexaazatriphenylenhexacarbonitril (hat-(CN)6) mit CuI-Ionen über den Koordinationsmodus des hat-(CN)6-Liganden (Bipyridinchelatisierung oder einzähniges CN, siehe Bild). Die Art der Koordination hat einen direkten Einfluss auf den Oxidationszustand und die Reduktionspotentiale des hat-(CN)6-Liganden.

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