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Reaction of Ruthenium Ethyne-1,2-diyl Compounds with Bis(trimethylsilyl)acetylene Complexes of Titanocene and Zirconocene: Remarkable Transfer of a C2 Ligand

Authors

  • Christopher S. Griffith Dr.,

    1. Chemistry, School of Chemical and Biomedical Sciences, University of Western Australia, 35 Stirling Highway, Perth, WA, 6009, Australia, Fax: (+62) 8-6488-7247
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  • George A. Koutsantonis Dr.,

    1. Chemistry, School of Chemical and Biomedical Sciences, University of Western Australia, 35 Stirling Highway, Perth, WA, 6009, Australia, Fax: (+62) 8-6488-7247
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  • Brian W. Skelton Dr.,

    1. Chemistry, School of Chemical and Biomedical Sciences, University of Western Australia, 35 Stirling Highway, Perth, WA, 6009, Australia, Fax: (+62) 8-6488-7247
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  • Allan H. White Prof.

    1. Chemistry, School of Chemical and Biomedical Sciences, University of Western Australia, 35 Stirling Highway, Perth, WA, 6009, Australia, Fax: (+62) 8-6488-7247
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  • C.S.G. was the holder of an Australian Postgraduate Award.

Abstract

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Transfer eines Kohlenstoffliganden: Verbindung 1 entsteht mit reaktiven Metall-Ligand-Fragmenten, die aus Gruppe-4-Metallocenen erzeugt werden. Tropfenweise Zugabe von ethanolischer HCl zu einer Lösung von 1 in Toluol liefert in einer als bislang unbekannt erachteten C-C-Verknüpfung den Komplex 2.

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