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Self-Assembly of an Interlaced Triple-Stranded Molecular Braid with an Unprecedented Topology through Hydrogen-Bonding Interactions

Authors

  • Xin-Jun Luan,

    1. Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi'an, Shaanxi, 710069, P.R. China, Fax: (+86) 29-8837-3398
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  • Yao-Yu Wang Prof. Dr.,

    1. Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi'an, Shaanxi, 710069, P.R. China, Fax: (+86) 29-8837-3398
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  • Dong-Sheng Li Dr.,

    1. Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi'an, Shaanxi, 710069, P.R. China, Fax: (+86) 29-8837-3398
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  • Ping Liu Dr.,

    1. Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi'an, Shaanxi, 710069, P.R. China, Fax: (+86) 29-8837-3398
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  • Huai-Ming Hu Prof. Dr.,

    1. Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi'an, Shaanxi, 710069, P.R. China, Fax: (+86) 29-8837-3398
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  • Qi-Zhen Shi Prof. Dr.,

    1. Department of Chemistry, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi'an, Shaanxi, 710069, P.R. China, Fax: (+86) 29-8837-3398
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  • Shie-Ming Peng Prof. Dr.

    1. Department of Chemistry, National Taiwan University, Taiwan
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  • This work was supported by the National Natural Science Foundation of China (No. 20471048) and TRAPOYT.

Abstract

original image

Molekulares Weben: Beim Mischen eines CuII-Komplexes mit Schaufelrad-Struktur mit einem hochflexiblen, neutralen 1,3-Bis(4-pyridyl)propan-Liganden im Verhältnis 1:2 entsteht ein verkettetes Gebilde, das genau wie ein Haarzopf aussieht (siehe Strukturbild). Die drei Stränge werden durch Wasserstoffbrücken zusammengehalten.

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