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Preparation of a Hydroperoxo Zinc(II) Intermediate

Authors

  • Akira Wada Dr.,

    1. Department of Applied Chemistry, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan, Fax: (+81) 52-735-5209
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  • Syuhei Yamaguchi Dr.,

    1. Department of Applied Chemistry, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan, Fax: (+81) 52-735-5209
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  • Koichiro Jitsukawa Prof.,

    1. Department of Applied Chemistry, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan, Fax: (+81) 52-735-5209
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  • Hideki Masuda Prof.

    1. Department of Applied Chemistry, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan, Fax: (+81) 52-735-5209
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  • This work was supported partly by a Grant-in-Aid for Scientific Research from the Ministry of Education, Science, Sports, and Culture of Japan and supported in part by a grant from the NITECH 21st Century COE Program, to which our thanks are due.

Abstract

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Drei Beine und vier Zähne: Der vierzähnige Tripodligand Bis[(6-Neopentylamino-2-pyridyl)methyl][(2-pyridyl)methyl]amin (H2bnpa) wurde zur Synthese einer neuartigen {Zn-OOH}-Spezies genutzt. Das Intermediat der Reaktion von [Zn(H2bnpa)(OH)]+ mit H2O2 (siehe Schema) wurde mit einer Kombination aus 1H-NMR-Spektroskopie und ESI-Massenspektrometrie charakterisiert. Seine Umsetzung mit CO2 lieferte [{Zn2+(H2bnpa)}2(CO42−)](ClO4)2.

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