Tetraarylphosphonium Halides as Arylating Reagents in Pd-Catalyzed Heck and Cross-Coupling Reactions

Authors

  • Lee Kyoung Hwang,

    1. Center for Molecular Design and Synthesis (CMDS), Department of Chemistry and School of Molecular Science (BK 21), Korea Advanced Institute of Science and Technology (KAIST), Daejeon 305-701, Korea, Fax: (+82) 42-869-2810
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  • Youngim Na,

    1. Center for Molecular Design and Synthesis (CMDS), Department of Chemistry and School of Molecular Science (BK 21), Korea Advanced Institute of Science and Technology (KAIST), Daejeon 305-701, Korea, Fax: (+82) 42-869-2810
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  • Junseong Lee,

    1. Center for Molecular Design and Synthesis (CMDS), Department of Chemistry and School of Molecular Science (BK 21), Korea Advanced Institute of Science and Technology (KAIST), Daejeon 305-701, Korea, Fax: (+82) 42-869-2810
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  • Youngkyu Do Prof.,

    1. Center for Molecular Design and Synthesis (CMDS), Department of Chemistry and School of Molecular Science (BK 21), Korea Advanced Institute of Science and Technology (KAIST), Daejeon 305-701, Korea, Fax: (+82) 42-869-2810
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  • Sukbok Chang Prof.

    1. Center for Molecular Design and Synthesis (CMDS), Department of Chemistry and School of Molecular Science (BK 21), Korea Advanced Institute of Science and Technology (KAIST), Daejeon 305-701, Korea, Fax: (+82) 42-869-2810
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  • This research was supported by the Center for Molecular Design and Synthesis at KAIST.

Abstract

original image

Hoch effizient: Tetraarylphosphoniumhalogenide, Ar4P+X, als arylierende Reagentien übertragen hoch effizient eine Arylgruppe in Pd-katalysierten Reaktionen mit Olefinen, Organoborverbindungen und terminalen Alkinen (siehe Schema).

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