[Re12CS17(CN)6]n (n=6, 8): A Sulfido–Cyanide Rhenium Cluster with an Interstitial Carbon Atom

Authors

  • Yuri V. Mironov Dr.,

    1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3, Acad. Lavrentiev pr., 630090 Novosibirsk, Russia, Fax: (+7) 3833-309489
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  • Nikolai G. Naumov Dr.,

    1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3, Acad. Lavrentiev pr., 630090 Novosibirsk, Russia, Fax: (+7) 3833-309489
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  • Svetlana G. Kozlova Dr.,

    1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3, Acad. Lavrentiev pr., 630090 Novosibirsk, Russia, Fax: (+7) 3833-309489
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  • Sung-Jin Kim Prof.,

    1. Department of Chemistry, Ewha Womans University, Seoul 120-750, Korea, Fax: (+82) 2-3277-2384
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  • Vladimir E. Fedorov Prof.

    1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3, Acad. Lavrentiev pr., 630090 Novosibirsk, Russia, Fax: (+7) 3833-309489
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  • This work was supported by the Russian Foundation for Basic Research (grants 05-03-08090 and 05-03-32123), the International Cooperation Research Program of the Ministry of Science & Technology of Korea (grant M60403000099-04A0100-02310), and the Division of Chemistry and Sciences on Materials of RAS (project No. 15 of Program 4.1). The authors are grateful to the Boreskov Institute of Catalysis SB RAS for an opportunity to use the ADF program.

Abstract

original image

Die Cyanidcluster [Re12CS17(CN)6]n (n=8 oder 6) könnten als Bausteine für polymere Materialien dienen. Sie entstehen aus ReS2 in geschmolzenem KCN bei 750 °C. Die Clustereinheit umfasst zwei {Re6}-Oktaeder, die durch drei μ2-S-Brücken und ein interstitielles μ6-C-Atom verbunden sind (siehe Bild).

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