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Heteroditopic Rebek's Imide Directs the Reactivity of Homoditopic Olefins within Desolvated Quaternary Assemblies in the Solid State†

  1. Dushyant B. Varshney,
  2. Xiuchun Gao,
  3. Tomislav Friščić,
  4. Leonard R. MacGillivray Prof.

Article first published online: 19 DEC 2005

DOI: 10.1002/ange.200502294

Issue

Angewandte Chemie

Angewandte Chemie

Volume 118, Issue 4, pages 662–666, January 16, 2006

Additional Information

How to Cite

Varshney, D. B., Gao, X., Friščić, T. and MacGillivray, L. R. (2006), Heteroditopic Rebek's Imide Directs the Reactivity of Homoditopic Olefins within Desolvated Quaternary Assemblies in the Solid State. Angewandte Chemie, 118: 662–666. doi: 10.1002/ange.200502294

Author Information

  1. Department of Chemistry, University of Iowa, Iowa City, IA 52242-1294, USA, Fax: (+1) 319-335-1270

  1. †

    We are grateful to the National Science Foundation (CAREER Award, L.R.M., DMR-0133138) for funding. Acknowledgement is also made to the Research Corporation (Research Innovation Award) for financial support.

Publication History

  1. Issue published online: 11 JAN 2006
  2. Article first published online: 19 DEC 2005
  3. Manuscript Received: 30 JUN 2005

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Keywords:

  • Cycloadditionen;
  • Festkörperreaktionen;
  • Rezeptoren;
  • Selbstorganisation;
  • Topochemie

Graphical Abstract

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Eine seltene Einkristall-Einkristall-Transformation hat die [2+2]-Photodimerisierung homoditoper Olefine (trans-1,2-Bis(4-pyridyl)ethylen) zur Folge, die mithilfe von Rebeks Imid in H-Brücken-gebundenen Komplexen zusammengeführt und vororganisiert wurden. Dabei entsteht ein rctt-Tetrakis(4-pyridyl)cyclobutan (siehe Bild) stereospezifisch mit bis zu 100 % Ausbeute.

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