A Germanate Framework Containing 24-Ring Channels, Ni[BOND]Ge Bonds, and Chiral [Ni@Ge14O24(OH)3] Cluster Motifs Transferred from Chiral Metal Complexes

Authors

  • Zhi-En Lin,

    1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China, Fax: (+86) 591-8371-0051
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  • Jie Zhang Prof. Dr.,

    1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China, Fax: (+86) 591-8371-0051
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  • Jing-Tai Zhao Prof. Dr.,

    1. State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, P. R. China
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  • Shou-Tian Zheng,

    1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China, Fax: (+86) 591-8371-0051
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  • Chun-Yang Pan,

    1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China, Fax: (+86) 591-8371-0051
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  • Guo-Ming Wang,

    1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China, Fax: (+86) 591-8371-0051
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  • Guo-Yu Yang Prof. Dr.

    1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China, Fax: (+86) 591-8371-0051
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  • This work was supported by the NNSF of China (Nos. 20473093 and 20271050), the Talents Program of Chinese Academy of Sciences, and the NSF of Fujian Province (Nos. E0510030 and E0210029).

Abstract

original image

Mikroporös: Mithilfe chiraler Metallkomplexe als Template wurden unter Solvothermalbedingungen zwei Germanate Ni@Ge14O24(OH)3⋅2 Ni(L)3 (L=Ethylendiamin, 1,2-Diaminopropan) erhalten. Die chiralen Ni@Ge14O24(OH)3-Cluster haben einen bisher unbekannten trigonal-bipyramidalen Ni@Ge5-Kern mit Ni-Ge-Bindungen und sind untereinander zu einem dreidimensionalen Germanat-Netzwerk mit Kanälen aus 24-gliedrigen Ringen verknüpft (siehe Bild).

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