Zuschrift

A Germanate Framework Containing 24-Ring Channels, Ni[BOND]Ge Bonds, and Chiral [Ni@Ge14O24(OH)3] Cluster Motifs Transferred from Chiral Metal Complexes†

  1. Zhi-En Lin1,
  2. Jie Zhang Prof. Dr.1,
  3. Jing-Tai Zhao Prof. Dr.2,
  4. Shou-Tian Zheng1,
  5. Chun-Yang Pan1,
  6. Guo-Ming Wang1,
  7. Guo-Yu Yang Prof. Dr.1

Article first published online: 5 OCT 2005

DOI: 10.1002/ange.200502432

Issue

Angewandte Chemie

Angewandte Chemie

Volume 117, Issue 42, pages 7041–7044, October 28, 2005

Additional Information

How to Cite

Lin, Z.-E., Zhang, J., Zhao, J.-T., Zheng, S.-T., Pan, C.-Y., Wang, G.-M. and Yang, G.-Y. (2005), A Germanate Framework Containing 24-Ring Channels, Ni[BOND]Ge Bonds, and Chiral [Ni@Ge14O24(OH)3] Cluster Motifs Transferred from Chiral Metal Complexes. Angew. Chem., 117: 7041–7044. doi: 10.1002/ange.200502432

Author Information

  1. 1

    State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China, Fax: (+86) 591-8371-0051

  2. 2

    State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, P. R. China

  1. †

    This work was supported by the NNSF of China (Nos. 20473093 and 20271050), the Talents Program of Chinese Academy of Sciences, and the NSF of Fujian Province (Nos. E0510030 and E0210029).

Publication History

  1. Issue published online: 25 OCT 2005
  2. Article first published online: 5 OCT 2005
  3. Manuscript Received: 12 JUL 2005

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Keywords:

  • Germanium;
  • Mikroporöse Materialien;
  • Nickel;
  • Solvothermalsynthese;
  • Templatsynthese
Thumbnail image of graphical abstract

Mikroporös: Mithilfe chiraler Metallkomplexe als Template wurden unter Solvothermalbedingungen zwei Germanate Ni@Ge14O24(OH)3⋅2 Ni(L)3 (L=Ethylendiamin, 1,2-Diaminopropan) erhalten. Die chiralen Ni@Ge14O24(OH)3-Cluster haben einen bisher unbekannten trigonal-bipyramidalen Ni@Ge5-Kern mit Ni-Ge-Bindungen und sind untereinander zu einem dreidimensionalen Germanat-Netzwerk mit Kanälen aus 24-gliedrigen Ringen verknüpft (siehe Bild).

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