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An Unexpected Photoelectronic Effect from [Co(en)3]2(Zr2F12)(SiF6)⋅4 H2O, a Compound Containing an H-Bonded Assembly of Discrete [Co(en)3]3+, (Zr2F12)4−, and (SiF6)2− Ions

Authors

  • Yu Du,

    1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China, Fax: (+86) 431-516-8608
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  • Min Yang,

    1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China, Fax: (+86) 431-516-8608
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  • Jihong Yu Prof.,

    1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China, Fax: (+86) 431-516-8608
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  • Qinhe Pan,

    1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China, Fax: (+86) 431-516-8608
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  • Ruren Xu Prof.

    1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China, Fax: (+86) 431-516-8608
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  • This work was supported by the National Natural Science Foundation of China and the State Basic Research Project of China (G2000077507). The authors thank Prof. Dejun Wang and Prof. Yubai Bai for their helpful discussions.

Abstract

original image

Wasserstoffbrückennetzwerk: Eine Hydrothermalsynthese lieferte die Titelverbindung, die aus einem wasserstoffverbrückten Netzwerk von diskreten [Co(en)3]3+-, (Zr2F12)4−- und (SiF6)2−-Ionen besteht und einen ungewöhnlichen photoelektronischen Effekt im Nah-UV-Bereich zeigt (siehe Bild).

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