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Surface Modification of a Six-Capped Body-Centered Cube Ni9W6 Cluster: Structure and Single-Molecule Magnetism

Authors


  • This work was supported by Korea Research Foundation Grant funded by Korea Government (MOEHRD, Basic Research Promotion Fund) (KRF-2005-015-C00223) and CRM-KOSEF. C.S.H thanks an Operation Program on Shared Research Equipment of KBSI and MOST.

Abstract

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Luftdicht verschlossen: In einem Ni9W6-High-Spin-Cluster (S=12) mit Cyanidbrücken sind die NiII- (grün) und WV-Ionen (violett) ferromagnetisch gekoppelt. Die Substitution der Solvensmoleküle an der Clusteroberfläche gegen 2,2′-Bipyridin ergab einen luftstabilen Ni9W6-Einzelmolekülmagnet.

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