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Configurationally Stable Molecular Propellers: First Resolution of Residual Enantiomers

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Errata

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  1. Errata: Configurationally Stable Molecular Propellers: First Resolution of Residual Enantiomers Volume 118, Issue 47, 8034, Article first published online: 27 November 2006

  • We thank Prof. M. Pierini (University of Rome “La Sapienza”) for a preliminary HPLC simulation, Prof. M. Gullotti (University of Milan) for CD spectra, and Jasco Europe Srl for technical assistance in HPLC experiments with a circular dichroism detector. T.B. is grateful to the Dipartimento di Chimica Organica e Industriale of the Università di Milano for hospitality. Financial support from project FIRB2003-RBNE033 KMIA is acknowledged.

Abstract

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Stoppen der Propeller: Allgemein herrscht Einigkeit darüber, dass sich Phosphanoxide und Phosphane mit drei identischen Arylgruppen wie achirale Verbindungen verhalten. Hier wird gezeigt, dass passend konzipierte Triarylphosphanoxide in Form konfigurativ stabiler Enantiomere isoliert werden können.

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