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Mapping the Landscape of Potentially Primordial Informational Oligomers: Oligodipeptides and Oligodipeptoids Tagged with Triazines as Recognition Elements

Authors

  • Gopi Kumar Mittapalli Dr.,

    1. Department of Chemistry and The Skaggs Institute for Chemical Biology, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, CA 92037, USA, Fax: (+1) 858-784-9573
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  • Kondreddi Ravinder Reddy Dr.,

    1. Department of Chemistry and The Skaggs Institute for Chemical Biology, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, CA 92037, USA, Fax: (+1) 858-784-9573
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  • Hui Xiong Dr.,

    1. Department of Chemistry and The Skaggs Institute for Chemical Biology, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, CA 92037, USA, Fax: (+1) 858-784-9573
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  • Omar Munoz Dr.,

    1. Department of Chemistry and The Skaggs Institute for Chemical Biology, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, CA 92037, USA, Fax: (+1) 858-784-9573
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  • Bo Han Dr.,

    1. Laboratorium für Organische Chemie, Eidgenössische Technische Hochschule, HCI Hönggerberg, 8093 Zürich, Switzerland, Fax: (+41) 1-632-1043
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  • Francesco De Riccardis Prof. Dr.,

    1. Department of Chemistry and The Skaggs Institute for Chemical Biology, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, CA 92037, USA, Fax: (+1) 858-784-9573
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  • Ramanarayanan Krishnamurthy Prof. Dr.,

    1. Department of Chemistry and The Skaggs Institute for Chemical Biology, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, CA 92037, USA, Fax: (+1) 858-784-9573
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  • Albert Eschenmoser Prof. Dr.

    1. Department of Chemistry and The Skaggs Institute for Chemical Biology, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, CA 92037, USA, Fax: (+1) 858-784-9573
    2. Laboratorium für Organische Chemie, Eidgenössische Technische Hochschule, HCI Hönggerberg, 8093 Zürich, Switzerland, Fax: (+41) 1-632-1043
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  • Chemistry of α-Aminonitriles, Part 45. For part 44, see reference  1a; for part 43, see reference  1b. This work was supported by the Skaggs Research Foundation. G.K.M., K.R.R., H.X., O.M., and F.D.R. are Skaggs Postdoctoral Fellows.

Abstract

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Paarbildung: Oligodipeptid-, Oligodesoxydipeptid- oder Oligodipeptoidgerüste, die mit dem 2,4-Diaminotriazinkern markiert wurden, bilden starke Paare mit komplementärer DNA und RNA. Der 2,4-Dioxotriazinkern fungiert dagegen in diesen Systemen nicht als Nucleobase.

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