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Self-Assembly of Nanometer-Scale [Cu24I10L12]14+ Cages and Ball-Shaped Keggin Clusters into a (4,12)-Connected 3D Framework with Photoluminescent and Electrochemical Properties

Authors

  • Xin-Long Wang Dr.,

    1. Key Laboratory of Polyoxometalate Science of Ministry of Education, Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin, 130024, China, Fax: (+86) 431-509-8787
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  • Chao Qin Dr.,

    1. Key Laboratory of Polyoxometalate Science of Ministry of Education, Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin, 130024, China, Fax: (+86) 431-509-8787
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  • En-Bo Wang Prof.,

    1. Key Laboratory of Polyoxometalate Science of Ministry of Education, Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin, 130024, China, Fax: (+86) 431-509-8787
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  • Zhong-Min Su Prof.,

    1. Key Laboratory of Polyoxometalate Science of Ministry of Education, Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin, 130024, China, Fax: (+86) 431-509-8787
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  • Yang-Guang Li Dr.,

    1. Key Laboratory of Polyoxometalate Science of Ministry of Education, Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin, 130024, China, Fax: (+86) 431-509-8787
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  • Lin Xu Prof.

    1. Key Laboratory of Polyoxometalate Science of Ministry of Education, Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin, 130024, China, Fax: (+86) 431-509-8787
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  • This work was financially supported by the National Natural Science Foundation of China (No. 20371011).

Abstract

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Brückenschlag: Eine Brücke zwischen der Polyoxometallatchemie und Kupferhalogenidclustern repräsentiert das (4,12)-verknüpfte dreidimensionale Netzwerk (NH4)[Cu24I10L12][PMoV2MoVI10O40]3, das durch kovalente Verknüpfung von nanoskaligen Keggin-Anionen und [Cu24I10L12]14+-Clustern aufgebaut wurde (siehe Bild; L: mehrzähniger N-heterocyclischer Ligand). Das Netzwerk zeigt bemerkenswerte elektrochemische und Photolumineszenz-Eigenschaften.

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