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A Trimetallic Fulvalene-Bridged Dizirconocene–Gallium Complex

Authors

  • Brandon Quillian,

    1. Department of Chemistry and The Center for Computational Chemistry, The University of Georgia, Athens, GA 30602-2556, USA, Fax: (+1) 706-542-9454
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  • Yuzhong Wang Dr.,

    1. Department of Chemistry and The Center for Computational Chemistry, The University of Georgia, Athens, GA 30602-2556, USA, Fax: (+1) 706-542-9454
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  • Chaitanya S. Wannere Dr.,

    1. Department of Chemistry and The Center for Computational Chemistry, The University of Georgia, Athens, GA 30602-2556, USA, Fax: (+1) 706-542-9454
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  • Pingrong Wei Dr.,

    1. Department of Chemistry and The Center for Computational Chemistry, The University of Georgia, Athens, GA 30602-2556, USA, Fax: (+1) 706-542-9454
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  • Paul von Ragué Schleyer Prof. Dr.,

    1. Department of Chemistry and The Center for Computational Chemistry, The University of Georgia, Athens, GA 30602-2556, USA, Fax: (+1) 706-542-9454
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  • Gregory H. Robinson Prof. Dr.

    1. Department of Chemistry and The Center for Computational Chemistry, The University of Georgia, Athens, GA 30602-2556, USA, Fax: (+1) 706-542-9454
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  • This work was supported by the National Science Foundation and the donors of the Petroleum Research Fund, administered by the American Chemical Society.

Abstract

original image

Eine Galliumbrücke: Die Röntgenstrukturanalyse von 1 (siehe Bild; Ga rosa, Zr blau, Cl grün, C gelb) ergab ein neuartiges Metall-Metall-Bindungsmotiv zwischen Gallium- und Zirconiumatomen: ein an zwei Zirconiumatome gebundenes Galliumatom. Spektroskopische und Computerdaten sprechen für das Vorliegen eines verbrückenden Zr-H-Zr-Hydrids in 1, das bei der Einkristallstrukturanalyse nicht entdeckt wurde.

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