Zuschrift

Synthesis and Electrochemical Properties of Fullerene-Rich Nanoclusters Synthesized by Cobalt-Catalyzed Cyclotrimerization of Bis(aryl)alkyne Fullerodendrimers†

  1. Uwe Hahn Dr.2,
  2. Emmanuel Maisonhaute Dr.1,
  3. Christian Amatore Prof. Dr.1,
  4. Jean-François Nierengarten Dr.2

Article first published online: 19 DEC 2006

DOI: 10.1002/ange.200603765

Issue

Angewandte Chemie

Angewandte Chemie

Volume 119, Issue 6, pages 969–972, January 29, 2007

Additional Information

How to Cite

Hahn, U., Maisonhaute, E., Amatore, C. and Nierengarten, J.-F. (2007), Synthesis and Electrochemical Properties of Fullerene-Rich Nanoclusters Synthesized by Cobalt-Catalyzed Cyclotrimerization of Bis(aryl)alkyne Fullerodendrimers. Angewandte Chemie, 119: 969–972. doi: 10.1002/ange.200603765

Author Information

  1. 1

    UMR CNRS 8640 “PASTEUR”, Departement de Chimie, Ecole Normale Supérieure, Université Pierre et Marie Curie Paris 6, 24 rue Lhomond, 75231 Paris Cedex 05, France, Fax: (+33) 1-4432-3863

  2. 2

    Groupe de Chimie des Fullerènes et des Systèmes Conjugués, Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 4, France, Fax: (+33) 5-6155-3003

  1. †

    This work was supported by the CNRS (UPR 8241 and UMR 8640), the Ecole Normale Supérieure, the Université Pierre et Marie Curie, and a postdoctoral fellowship from the Deutscher Akademischer Austausch Dienst (DAAD) to U.H.

Publication History

  1. Issue published online: 22 JAN 2007
  2. Article first published online: 19 DEC 2006
  3. Manuscript Revised: 10 OCT 2006
  4. Manuscript Received: 13 SEP 2006

Funded by

  • CNRS. Grant Numbers: UPR 8241, UMR 8640
  • Ecole Normale Supérieure, the Université Pierre et Marie Curie

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Keywords:

  • Cyclovoltammetrie;
  • Dendrimere;
  • Elektrochemie;
  • Fullerene

Graphical Abstract

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Jede Menge Bälle: Bis zu 24 C60-Einheiten ließen sich durch cobaltkatalysierte Cyclotrimerisierung von Bis(aryl)alkin-Fullerodendrimeren um einen Hexaphenylbenzolkern anordnen (siehe Schema). Elektrochemische Untersuchungen ergaben, dass C60-Einheiten innerhalb eines Dendrimermoleküls äußerst effizient wechselwirken.

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