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Well-Designed Supramolecular Clusters Comprising Triphenylmethylamine and Various Sulfonic Acids

Authors

  • Norimitsu Tohnai Dr.,

    1. Department of Material & Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan, Fax: (+81) 6-6879-7404
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  • Yuji Mizobe,

    1. Department of Material & Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan, Fax: (+81) 6-6879-7404
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  • Michiko Doi,

    1. Department of Material & Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan, Fax: (+81) 6-6879-7404
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  • Shin-ichiro Sukata,

    1. Department of Material & Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan, Fax: (+81) 6-6879-7404
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  • Tomoaki Hinoue,

    1. Department of Material & Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan, Fax: (+81) 6-6879-7404
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  • Tetsuharu Yuge,

    1. Department of Material & Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan, Fax: (+81) 6-6879-7404
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  • Ichiro Hisaki Dr.,

    1. Department of Material & Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan, Fax: (+81) 6-6879-7404
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  • Yozo Matsukawa,

    1. Department of Material & Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan, Fax: (+81) 6-6879-7404
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  • Mikiji Miyata Prof. Dr.

    1. Department of Material & Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan, Fax: (+81) 6-6879-7404
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  • This work was supported by a Grant-in-Aid for Scientific Research in the Priority Areas “Super-Hierarchical Structures (466)” (no. 18039025) and “Molecular Nano Dynamics (432)” (no. 17034039) from the Ministry of Education, Culture, Sports, Science and Technology, Japan.

Abstract

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Mögliche Nanopartikelvorstufen: Triphenylmethylamin (TritylNH2) und viele Sulfonsäuren bilden im festen Zustand und in Lösung [4+4]-Ionenpaarcluster [R: unterschiedliche organische Reste (Ph beim Kalottenmodell)]. Die Formen und Größen dieser Cluster werden durch die Sulfonsäuresubstituenten bestimmt. Die Cluster lassen sich bequem und effizient herstellen; diese Methode könnte sich für die Synthese organischer Nanopartikel eignen.

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