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Self-Assembled Hybrid Oligo(p-phenylenevinylene)–Gold Nanoparticle Tapes

Authors

  • Jeroen van Herrikhuyzen,

    1. Laboratory for Macromolecular and Organic Chemistry, Eindhoven University of Technology, PO Box 513, 5600MB Eindhoven, The Netherlands, Fax: (+31) 40-245-1036
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  • Subi J. George Dr.,

    1. Laboratory for Macromolecular and Organic Chemistry, Eindhoven University of Technology, PO Box 513, 5600MB Eindhoven, The Netherlands, Fax: (+31) 40-245-1036
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  • Matthijn R. J. Vos,

    1. Laboratory for Macromolecular and Organic Chemistry and Soft Matter CryoTEM Research Unit, Eindhoven University of Technology, The Netherlands
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  • Nico A. J. M. Sommerdijk Dr.,

    1. Laboratory for Macromolecular and Organic Chemistry and Soft Matter CryoTEM Research Unit, Eindhoven University of Technology, The Netherlands
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  • Ayyappanpillai Ajayaghosh Dr.,

    1. Photosciences and Photonics Unit, Chemical Sciences and Technology Division, Regional Research Laboratory, CSIR, Trivandrum 695019, India
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  • Stefan C. J. Meskers Dr.,

    1. Laboratory for Macromolecular and Organic Chemistry, Eindhoven University of Technology, PO Box 513, 5600MB Eindhoven, The Netherlands, Fax: (+31) 40-245-1036
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  • Albertus P. H. J. Schenning Dr.

    1. Laboratory for Macromolecular and Organic Chemistry, Eindhoven University of Technology, PO Box 513, 5600MB Eindhoven, The Netherlands, Fax: (+31) 40-245-1036
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  • The research work in Eindhoven was supported by the Netherlands Organization for Scientific Research (NWO) through a grant from the Open Competition program. We acknowledge P. Bomans, E. N. M. van Leeuwen, N. E. Papen-Botterhuis, R. A. J. Janssen, and E. W. Meijer.

Abstract

original image

Informationsübertragung: Ein Hybridgel aus π-konjugierten Oligo(p-phenylenvinylen)-Bändern (OPV1 und OPV2) und Goldnanopartikeln wurde in Toluol mithilfe nichtkovalenter Wechselwirkungen aufgebaut (siehe Bild). Die enge Nachbarschaft der Metallpartikel zu den π-konjugierten Molekülen führt zu einer Übertragung von elektronischer Anregungsenergie von den Molekülen zum Metall im Gelzustand.

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