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A Terminal Nitride-to-Phosphide Conversion Sequence Followed by Tungsten Phosphide Functionalization Using a Diphenylphosphenium Synthon

Authors

  • Alexander R. Fox,

    1. Department of Chemistry, Room 6-435, Massachusetts Institute of Technology, 77 Massachusetts Ave., Cambridge, MA 02139-4307, USA, Fax: (+1) 617-258-5700
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  • Christopher R. Clough,

    1. Department of Chemistry, Room 6-435, Massachusetts Institute of Technology, 77 Massachusetts Ave., Cambridge, MA 02139-4307, USA, Fax: (+1) 617-258-5700
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  • Nicholas A. Piro,

    1. Department of Chemistry, Room 6-435, Massachusetts Institute of Technology, 77 Massachusetts Ave., Cambridge, MA 02139-4307, USA, Fax: (+1) 617-258-5700
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  • Christopher C. Cummins

    1. Department of Chemistry, Room 6-435, Massachusetts Institute of Technology, 77 Massachusetts Ave., Cambridge, MA 02139-4307, USA, Fax: (+1) 617-258-5700
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  • We gratefully acknowledge the U.S. National Science Foundation (CHE-0316823) for financial support.

Abstract

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Ligand verloren und gewonnen: Ein Wolframkomplex mit endständigem Nitridliganden wird in einer Eintopfsequenz von Atomtransferreaktionen (siehe Schema) in den Komplex mit endständigem Phosphidliganden umgewandelt. Der Phosphidkomplex wird anschließend durch Behandlung mit einem Phosphorelektrophil funktionalisiert. Der dabei gebildete phosphorreiche Komplex weist P-P-Mehrfachbindungscharakter auf.

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